Journal of Physical Chemistry p. 5301 - 5303 (1983)
Update date:2022-08-11
Topics:
Nakabayashi, Seiichiro
Itoh, Kiminori
Fujishima, Akira
Honda, Kenichi
Highly exothermic electron transfer rates were measured by semiconductor electrochemical techniques.Experiments demonstrate that the decreases in the electron transfer rates with the exothermicity of the reactions in so-called abnormal regions are much more moderate than the classical predictions, and that this is probably due to the effects of intramolecular vibrations such as C-H stretching and/or bending.
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