International Journal of Chemical Kinetics p. 311 - 320 (1995)
Update date:2022-08-16
Topics:
Sharma, Indu
Devra, Vijai
Gupta, Divya
Gangwal, C. M.
Sharma, P. D.
Silver(I) catalyzed oxidation of aspartic acid by cerium(IV) was studied in acid perchlorate medium.The stoichiometry of the reaction is represented by the eq. (i), (i) R-CHNH3+COOH + 2 Ce(IV) -H2O-> R-CHO + NH4+ + CO2 + 2 Ce(III) + 2 H+.Dimeric cerium(IV) species has been indicated and employed in calculations of monomeric cerium(IV) species concentrations.The reaction is second-order and uncatalyzed reaction also simultaneously occurs along with silver(I) catalyzed reaction conforming to the rate law (ii), (ii)
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