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Article
Interactions: From Nanosheets to Nanofibers. Langmuir 2012, 28,
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0697−10702.
Corresponding Author
17) Xu, J.; Wu, G.; Wang, Z.; Zhang, X. Generation of 2D Organic
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Microsheets from Protonated Melamine Derivatives: Suppression of
the Self Assembly of a Particular Dimension by Introduction of Alkyl
Chains. Chem. Sci. 2012, 3, 3227−3230.
Notes
The authors declare no competing financial interest.
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18) Govindaraju, T.; Avinash, M. B. Two-Dimensional Nano-
architectonics: Organic and Hybrid Materials. Nanoscale 2012, 4,
ACKNOWLEDGMENTS
6102−6117.
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(19) De Yoreo, J. J.; Vekilov, P. G. Principles of Crystal Nucleation
This work was financially supported by the National Basic
Research Program of China (2013CB834502), the Foundation
for Innovative Research Groups of the National Natural
Science Foundation of China (21121004), and the NSFC−
DFG joint grant (TRR61).
and Growth. Rev. Mineral. Geochem. 2003, 54, 57−93.
20) Dhanaraj, G.; Byrappa, K.; Prasad, V.; Dudley, M. Springer
Handbook of Crystal Growth; Springer: New York, 2010; Vol. 1, pp 4−
(
6
.
(21) Cubillas, P.; Anderson, M. W. Zeolites and Catalysis: Synthesis,
Reactions and Applications; Wiley-VCH: New York, 2010; Chapter 1,
pp 6−11.
REFERENCES
■
(
22) Penn, R. L.; Banfield, J. F. Imperfect Oriented Attachment:
(
2
1) Geim, A. K.; Novoselov, K. S. The Rise of Graphene. Nat. Mater.
007, 6, 183−191.
2) Rao, C. N.; Sood, A. K.; Subrahmanyam, K. S.; Govindaraj, A.
Dislocation Generation in Defect-Free Nanocrystals. Science 1998,
81, 969−971.
23) Pina, C. M.; Becker, U.; Risthaus, P.; Bosbach, D.; Putnis, A.
Molecular-Scale Mechanisms of Crystal Growth in Barite. Nature
998, 395, 483−486.
24) Malkin, A. J.; Kuznetsov, Y. G.; McPherson, A. In Situ Atomic
2
(
(
Graphene: the New Two-Dimensional Nanomaterial. Angew. Chem.,
Int. Ed. Engl. 2009, 48, 7752−7777.
3) Allen, M. J.; Tung, V. C.; Kaner, R. B. Honeycomb Carbon: A
Review of Graphene. Chem. Rev. 2010, 110, 132−145.
4) Osada, M.; Sasaki, T. Two-Dimensional Dielectric Nanosheets:
Novel Nanoelectronics from Nanocrystal Building Blocks. Adv. Mater.
012, 24, 210−228.
5) Kimizuka, N.; Kawasaki, T.; Hirata, K.; Kunitake, T. Supra-
1
(
(
Force Microscopy Studies of Surface Morphology, Growth Kinetics,
Defect Structure and Dissolution in Macromolecular Crystallization. J.
(
Cryst. Growth 1999, 196, 471−488.
2
(
2+
(25) Davis, K. J.; Dove, P. M.; De Yoreo, J. J. The Role of Mg as an
Impurity in Calcite Growth. Science 2000, 290, 1134−1137.
molecular Membranes. Spontaneous Assembly of Aqueous Bilayer
Membrane via Formation of Hydrogen Bonded Pairs of Melamine and
Cyanuric Acid Derivatives. J. Am. Chem. Soc. 1998, 120, 4094−4104.
(26) Shoaee, M.; Agger, J. R.; Anderson, M. W.; Attfield, M. P.
̈
̂ ̀
Crystal Form, Defects and Growth of the Metal Organic Framework
HKUST-1 Revealed by Atomic Force Microscopy. CrystEngComm
(
6) Song, B.; Wang, Z.; Chen, S.; Zhang, X.; Fu, Y.; Smet, M.;
2
(
008, 10, 646−648.
Dehaen, W. The Introduction of π−π Stacking Moieties for
Fabricating Stable Micellar Structure: Formation and Dynamics of
Disklike Micelles. Angew. Chem., Int. Ed. 2005, 44, 4731−4735.
7) Yip, H. L.; Ma, H.; Jen, A. K.; Dong, J.; Parviz, B. A. Two-
Dimensional Self-Assembly of 1-Pyrylphosphonic Acid: Transfer of
Stacks on Structured Surface. J. Am. Chem. Soc. 2006, 128, 5672−5679.
8) Davis, R.; Berger, R.; Zentel, R. Two-Dimensional Aggregation of
Organogelators Induced by Biaxial Hydrogen-Bonding Gives Supra-
molecular Nanosheets. Adv. Mater. 2007, 19, 3878−3881.
9) Zhong, C.; Wang, J.; Wu, N.; Wu, G.; Zavalij, P. Y.; Shi, X. Anion
Bridged Nanosheet from Self-Assembled G-Quadruplexes. Chem.
Commun. 2007, 3148−3150.
10) Chen, Y.; Zhu, B.; Zhang, F.; Han, Y.; Bo, Z. Hierarchical
27) Cubillas, P.; Holden, M. A.; Anderson, M. W. Crystal Growth
Studies on Microporous Zincophosphate-Faujasite Using Atomic
Force Microscopy. Cryst. Growth Des. 2011, 11, 3163−3171.
(
(28) Thurston, J. T.; Dudley, J. R.; Kaiser, D. W.; Hechenbleikner, I.;
Schaefer, F. C.; Holm-Hansen, D. Cyanuric Chloride Derivatives. I.
Aminochloro-s-triazines. J. Am. Chem. Soc. 1951, 73, 2981−2983.
(
(29) Baliani, A.; Peal, V.; Gros, L.; Brun, R.; Kaiser, M.; Barrett, M.
P.; Gilbert, I. H. Novel Functionalized Melamine-based Nitrohetero-
cycles: Synthesis and Activity against Trypanosomatid Parasites. Org.
Biomol. Chem. 2009, 7, 1154−1166.
(
(
Supramolecular Self-Assembly of Nanotubes and Layered Sheets.
Angew. Chem., Int. Ed. 2008, 47, 6015−6018.
(
11) Lee, E.; Kim, J. K.; Lee, M. Reversible Scrolling of Two-
Dimensional Sheets from the Self-Assembly of Laterally Grafted
Amphiphilic Rods. Angew. Chem., Int. Ed. 2009, 48, 3657−3660.
(
12) An, Q.; Chen, Q.; Zhu, W.; Li, Y.; Tao, C. A.; Yang, H.; Li, Z.;
Wan, L.; Tian, H.; Li, G. A Facile Method for Preparing One-
Molecule-Thick Free-Standing Organic Nanosheets with a Regular
Square Shape. Chem. Commun. 2010, 46, 725−727.
(
13) Nam, K. T.; Shelby, S. A.; Choi, P. H.; Marciel, A. B.; Chen, R.;
Tan, L.; Chu, T. K.; Mesch, R. A.; Lee, B. C.; Connolly, M. D.;
Kisielowski, C.; Zuckermann, R. N. Free-Floating Ultrathin Two-
Dimensional Crystals from Sequence-Specific Peptoid Polymers. Nat.
Mater. 2010, 9, 454−460.
(
14) Han, M.; Hirade, T. Anisotropic Two-Dimensional Sheets
Assembled from Rod-Shaped Metal Complexes. Chem. Commun.
012, 48, 100−102.
15) Wu, G.; Verwilst, P.; Xu, J.; Xu, H.; Wang, R.; Smet, M.;
2
(
Dehaen, W.; Faul, C. F.; Wang, Z.; Zhang, X. Bolaamphiphiles Bearing
Bipyridine as Mesogenic Core: Rational Exploitation of Molecular
Architectures for Controlled Self-Assembly. Langmuir 2012, 28,
5
(
023−5230.
16) Liu, K.; Yao, Y.; Liu, Y.; Wang, C.; Li, Z.; Zhang, X. Self-
Assembly of Supra-Amphiphiles Based on Dual Charge-Transfer
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