10.1002/anie.201805924
Angewandte Chemie International Edition
COMMUNICATION
[9]
a) M. M. Titirici, M. Antonietti, Chem. Soc. Rev. 2010, 39, 103-116; b) P.
Kalyani, A. Anitha, Int. J. Hydrogen Energy 2013, 38, 4034-4045.
In summary, we reportedly demonstrate an organic synthetic
strategy to attain porous carbon (OSPC-1) which is entirely
different from the prevailing methods to prepare porous carbon
thereby favouring the design of porous carbon on molecular
level. This material is the only porous carbon that is constructed
from sp and sp3-hybridized carbon. Furthermore, we have
demonstrated that OSPC-1 is a highly promising anode material
for LIBs with high capacity, impressive rate capability, long cycle
life and the potential for improved safety performance. The
synthetic method, which is based upon versatile organic
polymerization, has potential to be extended to other 3D carbon
materials and thus spreads out the research frontiers to a new
family of porous carbon materials.
[10] a) Z. X. Ma, T. Kyotani, A. Tomita, Chem. Commun. 2000, 23, 2365-
2366; b) H. Nishihara, T. Kyotani, Adv. Mater. 2012, 23, 4473-4498.
[11] R. Ryoo, S. H. Joo, S. Jun, J. Phys. Chem. B 1999, 103, 7743-7746.
[12] a) G. N. Yushin, E. N. Hoffman, A. Nikitin, H. Ye, M. W. Barsoum, Y.
Gogotsi, Carbon, 2005, 43, 2075-2082; b) V. Presser, M. Heon, Y.
Gototsi, Adv. Funct. Mater. 2011, 21, 810-833.
[13] a) P. J. Waller, F. Gándara, O. M. Yaghi, Acc. Chem. Res. 2015, 48,
3053-3063; b) A. Schoedel, M. Li, D. Li, M. O’Keeffe, O. M. Yaghi,
Chem. Rev. 2016, 116, 12466-12535.
[14] R. Amemiya, K. Suwa, J. Toriyama, Y. Nishimura, M. Yamaguchi, J. the
Am. Chem. Soc. 2005, 127, 8252-8253.
[15] G. Eglinton, A. R. Galbraith, J. Chem. Soc. 1959, 182, 889-896.
[16] Y. X. Shao, Y. H. Cai, D. Dong, S. Wang, G. A. Siau, G. Q. X, Chem.
Phys. Lett. 2009, 482, 77-80.
[17] F. Tao, M. Qiao, Z. Li, L. Yang, J. Yu, G. Hai,Q. Guo, Phys. Rev. B
2003, 67, 115334.
Acknowledgements
[18] P. Zabek, J. Eberl, H. Kisch, Photochem. Photobiol. Sci. 2009, 8, 264-
269.
AT acknowledges the Royal Society. This work was supported
by the NSFC (Grant no.21390394, 21471065), the “111” project
(B07016). CJL is supported by EPSRC projects EP/N017188/1,
EP/M014452/1, EP/P027156/1. VV acknowledges the Thousand
Talents program (China) for support and the NSFC (no.
21571078). TB, SQ and VV acknowledge the support in the
framework of China-French joint laboratory “Zeolites”. The
synchrotron radiation experiments were performed at the
BL04B2 in the SPring-8 with the approval of the Japan
Synchrotron Radiation Research Institute (JASRI) (Proposal
Number 2017A0115).
[19] D. Chen, Z. Jiang, J. Geng, Q. Wang, D. Yang, Ind. & Eng. Chem. Res.
2007, 46, 2741-2746.
[20] Y. Taki, O. Takai, Thin Solid Films 1998, 316, 45-50.
[21] M. Häussler, R. Zheng,W. Y. Lam, H. Tong, H. Dong, B. Tang, J. Phys.
Chem. B 2004, 108, 10645-10650.
[22] A. Dato, V. Radmilovic, Z. H. Lee, J. Philips, M. Frenklach, Nano Lett.
2008, 8, 2012-2016.
[23] P. K. Chu, L. H. Li, Mater. Chem. Phys. 2006, 96, 253–277.
[24] A. D. Moller, F. E. Magaña, R. M. Sanchez, M. A. Borja, G. A. Hirata, L.
C. Araiza, J. Electron. Spectrosc. Relat. Phenom. 1999, 104, 61-66.
[25] A. P. Hitchcock, S. Johnston, T. Tyliszczak, C. C. Turci, M. Barbatti, A.
B. Rocha, C. E. Bielschowsky, J. Electron. Spectrosc. Relat. Phenom.
2002, 123, 303-314.
[26] V. Mortet, L. Zhang, M. Eckert, J. D`Haen, A. Soltani, M. Moreau, D.
Troadec, E. Neyts, J. D. Jaeger, J. Verbeeck, A. Bogaerts, G. V.
Tendeloo, K. Haenen, P. Wagner, Phys. Status Solidi A 2012, 209,
1675-1682.
Keywords: carbon • amorphous materials • semiconductors •
synthesis design • conducting materials
[1]
[2]
B. Sakintuna, Y. Yürüm, Ind. Eng. Chem. Res. 2005, 44, 2893-2902.
a) M. R. Benzigar, S. N. Talapaneni, S. Joseph, K. Ramadass, G. Singh,
J. Scaranto, U. Ravon, K. A. Bahily, A. Vinu, Chem. Soc. Rev. 2018, 47,
2680-2721; b) A. D. Roberts, X. Li, H. Zhang, Chem. Soc. Rev. 2014,
43, 4341-4356.
[27] S. K. Jain, R. J. M. Pellenq, J. P. Pikunic, K. E. Gubbins, Langmuir
2006, 22, 9942-9948.
[28] P. Kowalczyk, A. P. Terzyk, P. A. Gauden, S. Furmaniak, M.
Wisniewski, A. Burian, L. Hawelek, K. Kaneko, A. V. Neimark, J. Phys.
Chem. C 2014, 118, 12996-13007.
[3]
[4]
C. Zhu, H. Li, S. Fu, D. Du, Y. Lin Chem. Soc. Rev. 2016, 45, 517-531.
W. Long, B. Fang, A. Ignaszak, Z. Wu, Y. Wang, D. Wilkinson, Chem.
Soc. Rev. 2017, 46, 7176-7190.
[29] J. M. H. Thomas, A. Trewin, J. Phys. Chem. C 2014, 118, 19712-19722.
[30] M. S. José, A. Emilio, D. G. Julian, G. Alberto, J. Javier, O. Pablo, S.-P.
Daniel, J. Phys.: Condens. Matter 2002, 14, 2745.
[5]
[6]
[7]
[8]
A. M. Stephan, T. P. Kumar, R. Ramesh, S. Thomas, S. K. Jeong, K. S.
Nahm, Mater. Sci. Eng. A. 2006, 430, 132-137.
[31] a) R. Raccichini, A. Varzi, S. Passerini, B. Nat. Mater. 2015, 14, 271-
279; b) S. T. Lee, Z. Lin, X. Jiang, Mater. Sci. Eng., R 1999, 25, 125-
154.
Y. J. Hwang, S. K. Jeong, K. S. Nahm, J. S. Shin, S. A. Manuel, J. Phys.
Chem. Solids, 2007, 68, 182-188.
[32] a) S. Megahed, J. Power Sources, 1994, 51, 79-104; b) S. Flandrois, B.
Simon, Carbon, 1999, 37, 165–180.
Y. S. Hu, P. Adelhelm, B. M. Smarsly, S. Hore, M. Antonietti, J. Maierm,
Adv. Funct. Mater. 2007, 17, 1873-1878.
[33] H. G. Buss, S. Y. Chan, N. A. Lynd, B. D. McCloskey, ACS Energy Lett.
2017, 2, 481-487.
S. H. Yeon, K. N. Jung, S. Yoon, K. H. Shin, C. S. Jin, J. Phys. Chem.
Solids 2013, 74, 1045-1055.
This article is protected by copyright. All rights reserved.