Angewandte
Chemie
centimeters can readily be patterned (see the Supporting
Information).
[8] U. Schmelmer, R. Jordan, W. Geyer, W. Eck, A. Gꢀlzhꢁuser, M.
Grunze, A. Ulman, Angew. Chem. 2003, 115, 577; Angew. Chem.
Int. Ed. 2003, 42, 559; H.-P. Brack, C. Padeste, M. Slaski, S.
Alkan, H. H. Solak, J. Am. Chem. Soc. 2004, 126, 1004; S. J. Ahn,
M. Kaholek, W.-K. Lee, B. LaMattina, T. H. LaBean, S.
Zauscher, Adv. Mater. 2004, 16, 2141; M. Kaholek, W.-K. Lee,
J. Feng, B. LaMattina, D. J. Dyer, S. Zauscher, Chem. Mater.
Received: December 12, 2006
Revised: February 23, 2007
Published online: May 29, 2007
2
006, 18, 3660.
Keywords: atomic force microscopy · lithography ·
polymer brushes · radical polymerization · self-assembly
[
9] M. Geissler, Y. Xia, Adv. Mater. 2004, 16, 1249.
10] M. Park, C. Harrison, P. M. Chaikin, R. A. Register, D. H.
Adamson, Science 1997, 276, 1401.
.
[
[
11] C. L. Haynes, R. P. Van Duyne, J. Phys. Chem. B 2001, 105, 5599.
[
1] B. Zhao, W. J. Brittain, Prog. Polym. Sci. 2000, 25, 677; G. K.
Jennings, E. L. Brantley, Adv. Mater. 2004, 16, 1983; S. Edmond-
son, V. L. Osborne, W. T. S. Huck, Chem. Soc. Rev. 2004, 33, 14.
2] O. Prucker, J. Rühe, Macromolecules 1998, 31, 592; O. Prucker, J.
Rühe, Macromolecules 1998, 31, 602.
[12] M. Gleiche, L. F. Chi, H. Fuchs, Nature 2000, 403, 173; S.
Lenhert, L. Zhang, J. Mueller, H. P. Wiesmann, G. Erker, H.
Fuchs, L. Chi, Adv. Mater. 2004, 16, 619.
[13] X. Chen, M. Hirtz, H. Fuchs, L. Chi, Adv. Mater. 2005, 17, 2881;
X. Chen, A. L. Rogach, D. V. Talapin, H. Fuchs, L. Chi, J. Am.
Chem. Soc. 2006, 128, 9592.
[14] A. Studer, Chem. Soc. Rev. 2004, 33, 267.
[15] K. Matyjaszewski, B. E. Woodworth, X. Zhang, S. G. Gaynor, Z.
Metzner, Macromolecules 1998, 31, 5955.
[16] C. Wetter, J. Gierlich, C. A. Knoop, C. Müller, T. Schulte, A.
Studer, Chem. Eur. J. 2004, 10, 1156; T. Schulte, K. O.
Siegenthaler, H. Luftmann, M. Letzel, A. Studer, Macromole-
cules 2005, 38, 6833.
[17] C. Devaux, J. P. Chapel, E. Beyou, P. Chaumont, Eur. Phys. J. E
2002, 7, 345.
[
[
[
[
3] C. J. Hawker, A. W. Bosman, E. Harth, Chem. Rev. 2001, 101,
3661.
4] K. Matyjaszewski, J. Xia, Chem. Rev. 2001, 101, 2921; M.
Kamigaito, T. Ando, M. Sawamoto, Chem. Rev. 2001, 101, 3689.
5] “Controlled/Living Radical Polymerization”: E. Rizzardo, J.
Chiefari, R. T. A. Mayadunne, G. Moad, S. H. Thang, ACS
Symp. Ser. 2000, 768, 278.
[
6] D. M. Jones, J. R. Smith, W. T. S. Huck, C. Alexander, Adv.
Mater. 2002, 14, 1130; T. A. von Werne, D. S. Germack, E. C.
Hagberg, V. V. Sheares, C. J. Hawker, K. R. Carter, J. Am. Chem.
Soc. 2003, 125, 3831; S. Edmondson, W. T. S. Huck, Adv. Mater.
[18] The experiment with 15 mol% 4 in the mixed phase showed
irregularities in the pattern formation.
2004, 16, 1327; F. Zhou, W. T. S. Huck, Chem. Commun. 2005,
5
999.
[19] Y. Tsujii, K. Ohno, S. Yamamoto, A. Goto, T. Fukuda in
Advances in Polymer Science, Vol. 197 (Ed.: R. Jordan),
Springer, Berlin, 2006, p. 1.
[
7] M. Husemann, M. Morrison, D. Benoit, J. Frommer, C. M. Mate,
W. D. Hinsberg, J. L. Hedrick, C. J. Hawker, J. Am. Chem. Soc.
2
000, 122, 1844; F. Zhou, L. Jiang, W. Liu, Q. Xue, Macromol.
[20] C. Yoshikawa, A. Goto, Y. Tsujii, T. Fukuda, T. Kimura, K.
Yamamoto, A. Kishida, Macromolecules 2006, 39, 2284.
Rapid Commun. 2004, 25, 1979; F. J. Xu, Y. Song, Z. P. Cheng,
X. L. Zhu, C. X. Zhu, E. T. Kang, K. G. Neoh, Macromolecules
2005, 38, 6254.
Angew. Chem. Int. Ed. 2007, 46, 5231 –5233
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