Tetrahedron Letters p. 4985 - 4988 (1980)
Update date:2022-08-17
Topics:
Baeckvall, Jan-E.
Karlsson, Ola
Ljunggren, Stig O.
Reaction of trans-1,2-dideuterioethene oxide (1) with carbon dioxide, using copper and nickel catalysts, and subsequent analysis of the product ethene carbonate-d2 (2) by microwave spectroscopy, shows that the copper-catalyzed reaction is stereo-specific (retention) whereas the nickel-catalyzed reaction is non-stereospecific.
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