6
Tetrahedron
The authors declare no conflict of interest.
15
García-Domínguez, P.; Fehr, L.; Rusconi, G.; Nevado, C.
Brunel, P.; Monot, J.; Kefalidis, C. E.; Maron, L.;
Chem. Sci. 2016, 7, 3914.
16
Acknowledgments
Martin-Vaca, B.; Bourissou, D. ACS Catal. 2017, 7, 2652.
17 Zhao, Y.; Qiu, J.; Tian, L.; Li, Z.; Fan, M.; Wang, J. ACS
Sus. Chem. Eng. 2016, 4, 5553.
This research was financially supported by JST CREST Grant
Number JPMJCR1522. The authors also would like to thank
18
Wang, M.-Y.; Song, Q.-W.; Ma, R.; Xie, J.-N.; He, L.-
N. Green Chem. 2016, 18, 282.
19
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Dimroth, P.; Pasedach, H. Ger. Pat 1964, 1164411.
Costa, M.; Chiusoli, G. P.; Rizzardi, M. Chem. Commun.
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Space filling images of PA1, PA2 and MC30 were
shown in Figure S37.
5135.
1. A novel air-stable, Cu-tethered macrocycle
(CuMC) catalyst possessing a large inner cavity
was successfully synthesized.
2. CuMC-catalyzed CO2-fixation reaction to
propargylamines proceeded under atmospheric
CO2 conditions.
3. CuMC exhibited unique substrate size selectivity
owing to its topological effects.