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Name	ISOBUTYL IODIDE	EINECS	208-160-5
CAS No.	513-38-2	Density	1.617 g/cm³
PSA	0.00000	LogP	2.07740
Solubility	insoluble in water	Melting Point	-93 °C
Formula	C₄H₉I	Boiling Point	120 °C at 760 mmHg
Molecular Weight	184.02	Flash Point	12.8 °C
Transport Information	UN 2391 3/PG 2	Appearance	clear colorless to light orange liquid
Safety	16-26-36-9-33	Risk Codes	11-36/37/38-20
Molecular Structure		Hazard Symbols	F,Xi,Xn
Synonyms	3-Iodo-2-methylpropane;NSC 8421;2-Methylpropyl iodide;1-Iodo-2-methylpropane;1-Iodoisobutane;2-Methyl-1-iodopropane;2-Methylpropan-1-yl iodide;	Article Data	28

ISOBUTYL IODIDE Synthetic route

: 4873-56-7
isobutyl p-toluenesulfonate

: 513-38-2
Isobutyl iodide

Conditions

Conditions	Yield
With sodium iodide In neat (no solvent) at 120℃; for 0.5h; Microwave irradiation;	99%

: 123-51-3
i-Amyl alcohol

A: 13423-15-9
3-methyltetrahydrofuran

B: 513-38-2
Isobutyl iodide

C: 590-86-3
isovaleraldehyde

Conditions

Conditions	Yield
With N-iodo-succinimide In chlorobenzene for 2h; Irradiation;	A 94% B 5% C 1%

: 78-83-1
2-methyl-propan-1-ol

: 603-35-0
triphenylphosphine

: 513-38-2
Isobutyl iodide

Conditions

Conditions	Yield
With quinoline; iodine In nitrobenzene	74%

: 78-83-1
2-methyl-propan-1-ol

: 513-38-2
Isobutyl iodide

Conditions

Conditions	Yield
With phosphoric acid; potassium iodide
With phosphorus; iodine Einw. das Reaktionsprodukt von gelbem Phosphor;
With iodophosphorus

: 556-56-9
allyl iodid

: 593-71-5
Chloroiodomethane

: 1068-55-9
isopropylmagnesium chloride

A: 75-30-9
2-iodo-propane

B: 513-38-2
Isobutyl iodide

C: 7766-51-0
4-iodobut-1-ene

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether at -40℃; for 4.5h; Product distribution;
In tetrahydrofuran at -40℃; for 4.5h;

...Expand

: 79-29-8
2,3-dimethylbutane

A: 513-38-2
Isobutyl iodide

B: 594-59-2
iodo-2 dimethyl-2,3 butane

C: 52670-34-5
tetramethyl-2,3,6,7 octane

D: 2300-25-6, 2300-27-8, 71486-02-7, 31295-00-8
rac-2,3-dimethyl-1-iodobutane

E: 52670-35-6
pentamethyl-2,3,3,5,6 heptane

F: 558-17-8
tert-Butyl iodide

Conditions

Conditions	Yield
With hydrogen iodide In solid matrix at -196.1℃; Product distribution; Irradiation; γ-radiolysis 60Co; or without HI;

...Expand

: 79-29-8
2,3-dimethylbutane

A: 513-38-2
Isobutyl iodide

B: 594-59-2
iodo-2 dimethyl-2,3 butane

C: 2300-25-6, 2300-27-8, 71486-02-7, 31295-00-8
rac-2,3-dimethyl-1-iodobutane

D: 558-17-8
tert-Butyl iodide

Conditions

Conditions	Yield
With hydrogen iodide In solid matrix at -196.1℃; Irradiation; γ-radiolysis (60Co); Further byproducts given;

: 78-77-3
Isobutyl bromide

: 513-38-2
Isobutyl iodide

Conditions

Conditions	Yield
With pyridine; tributyltin iodide at 125℃; Thermodynamic data; Equilibrium constant; Δ G;
With sodium iodide In acetone Reflux; Inert atmosphere;

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 24681-02-5
Diisobutoxy-ethylphosphin

A: 513-38-2
Isobutyl iodide

B: 77529-59-0
isobutyl ethyl(heptafluoropropyl)phosphinate

Conditions

Conditions	Yield
In octane Rate constant; Kinetics; Thermodynamic data; E (activ.); ΔH(excit.); ΔS(excit.); ΔG(excit.);

: 513-36-0
isobutyryl chloride

: 513-38-2
Isobutyl iodide

Conditions

Conditions	Yield
With pyridine; tributyltin iodide at 125℃; Thermodynamic data; Equilibrium constant; Δ G;

ISOBUTYL IODIDE Chemical Properties

Product Name: Isobutyl iodide
The MF of Isobutyl iodide (513-38-2) is C₄H₉I.

The MW of Isobutyl iodide (513-38-2) is 184.02.
Synonyms: ISOBUTYL IODIDE ; 1-IODOMETHYLPROPANE ; 1-IODO-2-METHYLPROPANE ; 1-Iodo-iso-butane ; iodomethylpropanes ; 1-iodo-2-methyl-propan ; 1-Jod-2-methylpropan ; 2-methylpropyliodide
Product Categories: Iodine Compounds
EINECS: 208-160-5
Flash Point: 12.8°C
Boiling Point: 120°C
Melting Point: -93°C
density: 1.599 g/mL at 25°C(lit.)
vapor density: 6 (vs air)
vapor pressure: 20 mm Hg (20°C)
refractive index: n20/D 1.496(lit.)
storage temp: Flammables area
Water Solubility: insoluble
Sensitive: Light Sensitive
Appearance: Clear, pink liquid.
Merck: 14,5144
BRN: 1730927

ISOBUTYL IODIDE Uses

Isobutyl iodide (513-38-2) is used as solvents, analytical reagents, organic synthesis of raw materials.

ISOBUTYL IODIDE Toxicity Data With Reference

1.	ihl-rat LC50:6700 mg/m3/4H	34ZIAG Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.,1969,756.
2.	ipr-rat LD50:1241 mg/kg	34ZIAG Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.,1969,756.
3.	ipr-mus LD50:594 mg/kg	34ZIAG Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.,1969,756.

ISOBUTYL IODIDE Consensus Reports

EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.

ISOBUTYL IODIDE Safety Profile

Moderately toxic by intraperitoneal route. Mildly toxic by inhalation. A flammable liquid. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of I⁻. See also IODIDES.
Safety information of Isobutyl iodide (513-38-2):
Hazard Codes

Xi,Xn
Risk Statements 11-36/37/38-20
R11: Highly Flammable
R36/37/38: Irritating to eyes, respiratory system and skin
R20: Harmful by inhalation
Safety Statements 16-26-36-9-33
S16: Keep away from sources of ignition - No smoking
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36: Wear suitable protective clothing
S9: Keep container in a well-ventilated place
S33: Take precautionary measures against static discharges
RIDADR UN 2391 3/PG 2
WGK Germany 3
RTECS TZ4250000
F 8-10-23
HazardClass 3
PackingGroup II
HS Code 29033080

ISOBUTYL IODIDE Standards and Recommendations

DOT Classification: 3; Label: Flammable Liquid

ISOBUTYL IODIDE Specification

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

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