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Cas Database |
| Name |
Lithium metaborate |
EINECS | 236-631-5 |
| CAS No. | 13453-69-5 | Density | 1.4 g/cm3 |
| PSA | 40.13000 | LogP | -0.88610 |
| Solubility | N/A | Melting Point |
845 °C(lit.) |
| Formula | LiBO2 | Boiling Point | N/A |
| Molecular Weight | 49.7508 | Flash Point | N/A |
| Transport Information | N/A | Appearance | white powder |
| Safety | 24/25 | Risk Codes | 20/21/22-41 |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
lithium,oxido(oxo)borane;Boric acid lithium salt;Lithium metaborate; |
Article Data | 7 |
Lithium metaborate Synthetic route
| Conditions | Yield |
|---|---|
| thermal decompn. in air at 115°C and in N2 atmosphere at 120°C; |
A
- 13453-69-5
lithium metaborate
B
- 7732-18-5
water
| Conditions | Yield |
|---|---|
| With oxygen byproducts: CO2; oxisative decompn. on heating; | |
| With O2 byproducts: CO2; oxisative decompn. on heating; |
| Conditions | Yield |
|---|---|
| In neat (no solvent, solid phase) heating in air (800°C); |
| Conditions | Yield |
|---|---|
| With cobalt(II) chloride at 20℃; |
| Conditions | Yield |
|---|---|
| In water at 20℃; for 1h; Schlenk technique; Inert atmosphere; Sonication; |
| Conditions | Yield |
|---|---|
| In methanol with exclusion of air in excess anhydrous methanol; between room temp. and boiling; by refluxing; | |
| In methanol with exclusion of air in excess anhydrous methanol; between room temp. and boiling; by refluxing; |
| Conditions | Yield |
|---|---|
| In water in concd.soln.; pptd. with alcohol; | |
| In water in concd.soln.; pptd. with alcohol; |
| Conditions | Yield |
|---|---|
| with anhydrous CH3OH; reflux; exclusion of air; addn. of dimethyl ether to filtrate; drying at room temp.; | |
| with anhydrous CH3OH; reflux; exclusion of air; addn. of dimethyl ether to filtrate; drying at room temp.; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) melting, cooling from 1198 K to 698 K (6 K/h); washing (hot distd. water); |
Lithium metaborate Specification
The Lithium metaborate, also known as Lithium Tetraborate, is an chemical compound with the formula LiBO2. It belongs to the product categories of Inorganics; ACS Grade Synthetic Reagents; Essential Chemicals; Inorganic Salts; Lithium; Routine Reagents; Lithium Salts; Metal and Ceramic Science; Salts. Its EINECS registry number is 236-631-5. With the CAS registry number 13453-69-5, its IUPAC name is lithium oxido(oxo)borane.
Physical properties of Lithium metaborate: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 2; (3)Rotatable Bond Count: 0; (4)Exact Mass: 50.015139; (5)MonoIsotopic Mass: 50.015139; (6)Topological Polar Surface Area: 40.1; (7)Heavy Atom Count: 4; (8)Formal Charge: 0; (9)Complexity: 13.5; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 2.
Preparation of Lithium metaborate: This chemical can be prepared by fused lithium hydroxide or lithium carbonate and boric acid in right chemistry proportion.
B2O + Li2CO3 = 2LiBO2 + CO2
Uses of Lithium metaborate: It can be used in borate fusion sample preparation of various samples for analysis by XRF, AAS, ICP-OES, ICP-AES and ICP-MS.
When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation, in contact with skin and if swallowed. In addition, there will be a risk of serious damage to eyes. When using it, you must avoid contact with skin and eyes.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [Li+].B(=O)[O-]
(2)InChI: InChI=1S/BO2.Li/c2-1-3;/q-1;+1
(3)InChIKey: HZRMTWQRDMYLNW-UHFFFAOYSA-N
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