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Lithium molybdate(VI)

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Name

Lithium molybdate(VI)

EINECS 236-977-7
CAS No. 13568-40-6 Density 2.66 g/mL at 25 °C(lit.)
PSA 80.26000 LogP -0.47520
Solubility soluble in water Melting Point 705 °C
Formula Li2MoO4 Boiling Point N/A
Molecular Weight 173.82 Flash Point N/A
Transport Information N/A Appearance white to almost white crystalline powder
Safety 26-37/39 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 13568-40-6 (Lithium molybdate(VI)) Hazard Symbols IrritantXi
Synonyms

Lithiummolybdate(VI) (Li2MoO4) (6CI,7CI);Molybdate (MoO42-), dilithium, (T-4)- (9CI);Molybdic acid (H2MoO4), dilithium salt (8CI);Dilithium molybdate (Li2MoO4);Dilithium molybdenum tetraoxide;Dilithium tetraoxomolybdate(2-);Lithiummolybdate;Lithium molybdate (Li2MoO4);Lithium molybdenum oxide (Li2MoO4);

Article Data 64

Lithium molybdate(VI) Synthetic route

molybdenum(VI) oxide

1310-65-2

lithium hydroxide

13568-40-6

lithium molybdate

Conditions
ConditionsYield
In water pH 7-7.5; 2 h boiling on water bath; filtering, drying;94%
In water pH 7-7.5; 2 h boiling on water bath; filtering, drying;94%
In neat (no solvent, solid phase) for 5 mo; not isolated, detected by XRD;
Heating;

molybdic acid

1310-66-3

lithium hydroxide monohydrate

13568-40-6

lithium molybdate

Conditions
ConditionsYield
In water H2MoO4*H2O (1 mmol) added to aq. soln. of LiOH*H2O (2 mmol), stirred for20 min; filtered, allowed to stant (air) at room temp. for 1 week;87%
554-13-2

lithium carbonate

molybdenum(VI) oxide

13568-40-6

lithium molybdate

Conditions
ConditionsYield
MoO3:Li2CO3 (1:1); reaction begins at 300°C;
heating (823 K);

lithium oxide

7439-98-7

molybdenum

13568-40-6

lithium molybdate

Conditions
ConditionsYield
byproducts: Li; above 1150 °C, Li2O a Mo crucible;
at 1320°C, in Mo vessel;
at 1320°C, in Mo vessel;

molybdenum(VI) oxide

lithium oxide

13568-40-6

lithium molybdate

Conditions
ConditionsYield
In neat (no solvent) mixing, firing in air (740K) in a silica crucible fo 48 h with one intermediate grinding;
In neat (no solvent) mixing of powdered and dried stoichiometric amounts of starting materials, firing in air at around 740 K for 48 h;

molybdenum(VI) oxide

lithium oxide

A

13568-40-6

lithium molybdate

B

Li4MoO5

Conditions
ConditionsYield
at 350°C, Li2O:MoO3 mol ratio beetween 1:1 and 2:1;
at 350°C, Li2O:MoO3 mol ratio beetween 1:1 and 2:1;
1310-66-3

lithium hydroxide monohydrate

molybdenum(VI) oxide

13568-40-6

lithium molybdate

Conditions
ConditionsYield
In water standing (some d); recrystn. (H2O);
In neat (no solvent) byproducts: H2O; ground under ambient conditions in air for 1 min, allowed to dry at roomtemp. for ca 1 h;

ammonium molybdate

1310-65-2

lithium hydroxide

13568-40-6

lithium molybdate

Conditions
ConditionsYield
With ammonium molybdate In water
With ammonium molybdate In water

lithium oxide

7439-98-7

molybdenum

A

13568-40-6

lithium molybdate

B

7439-93-2

lithium

Conditions
ConditionsYield
above 1150°C;
above 1150°C;

lithium sulfate

calcium molybdate

13568-40-6

lithium molybdate

Conditions
ConditionsYield
In not given byproducts: CaSO4; equilibrium react. at 25°C;;
In not given byproducts: CaSO4; equilibrium react. at 25°C;;

Lithium molybdate(VI) Specification

The CAS register number of Lithium molybdate(VI) is 13568-40-6. It also can be called as Dilithium molybdate and the IUPAC name about this chemical is dilithium dioxido(dioxo)molybdenum. The molecular formula about this chemical is Li2MoO4 and the molecular weight is 173.82. It belongs to the following product categories, such as Alternative Energy; Catalysis and Inorganic Chemistry; Electrode MaterialsChemical Synthesis; Materials Science; Molybdenum and so on.

Physical properties about Lithium molybdate(VI) are: (1)#H bond acceptors: 4; (2)#H bond donors: 2; (3)Polar Surface Area: 74.6Å2; (4)H-Bond Acceptor: 4; (5)Exact Mass: 175.917074; (6)MonoIsotopic Mass: 175.917074; (7)Topological Polar Surface Area: 80.3; (8)Heavy Atom Count: 7; (9)Complexit: 62.2; (10)Covalently-Bonded Unit Count: 3.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [Li+].[Li+].[O-][Mo]([O-])(=O)=O
(2)InChI: InChI=1/2Li.Mo.4O/q2*+1;;;;2*-1/r2Li.MoO4/c;;2-1(3,4)5/q2*+1;-2
(3)InChIKey: NMHMDUCCVHOJQI-FFXFYZCHAF
(4)Std. InChI: InChI=1S/2Li.Mo.4O/q2*+1;;;;2*-1
(5)Std. InChIKey: NMHMDUCCVHOJQI-UHFFFAOYSA-N

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