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Methoxymethylamine

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Name

Methoxymethylamine

EINECS 214-255-2
CAS No. 1117-97-1 Density 0.796 g/cm3
PSA 21.26000 LogP 0.15810
Solubility N/A Melting Point 97℃
Formula C2H7NO Boiling Point 2.908 °C at 760 mmHg
Molecular Weight 61.0837 Flash Point -28.618 °C
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 1117-97-1 (N-methoxymethylamine) Hazard Symbols N/A
Synonyms

Hydroxylamine, N,O-dimethyl-;Methoxyamine, N-methyl-;Methylmethoxyamine;N,O-Dimethylhydroxylamine;N-Methoxy-N-methylamine;N-Methoxymethanamine;N-Methoxymethylamine;N-Methylmethoxyamine;O,N-Dimethylhydroxylamine;Methylamine,N-methoxy- (6CI,7CI,8CI);(Methoxyamino)methane;

Article Data 28

Methoxymethylamine Synthetic route

6638-79-5

N,O-dimethylhydroxylamine*hydrochloride

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
With sodium hydroxide In N,N-dimethyl-formamide distillation;92%
With triethanolamine at 150℃;81%
With triethanolamine In ethylene glycol at 150℃;81%
6919-62-6

ethyl N-methoxy-N-methylcarbamate

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
With hydrogenchloride
1576-17-6

N-methoxy-N-methyl-N'-phenylurea

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
With aniline at 150℃;
34893-99-7

N,O-Dimethylhydroxymethan

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
With potassium hydroxide
5725-96-2

N,N-dimethylhydroxylamine

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
at 298℃; Thermodynamic data; rearrangement of N-oxide to O-alkyl hydroxylamines , ΔH, ΔS, ΔG;
16339-12-1

N-nitroso-N,O-dimethylhydroxylamine

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
With perchloric acid; ammonium sulfamate; sodium thiocyanide at 50℃; Rate constant;
With 2,2-dicloroethanol In cyclohexane at 25℃; Kinetics; Equilibrium constant; Decomposition;
162189-76-6

β-(N-methyl-N-methoxyamine)-α-nitrostilbene

A

96746-56-4

(E)-β-Methoxy-α-nitrostilbene

B

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
In water; dimethyl sulfoxide at 20℃; Equilibrium constant;
O.N-dimethyl-oxy urethane

O.N-dimethyl-oxy urethane

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
With potassium hydroxide durch Verseifung;
6919-62-6

ethyl N-methoxy-N-methylcarbamate

alcoholic KOH-solution

alcoholic KOH-solution

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
Verseifung;
78191-00-1

N-Methoxy-N-methylacetamide

1117-97-1

N,0-dimethylhydroxylamine

Conditions
ConditionsYield
In ethanol
With sulfuric acid at 76℃; for 5h;

Methoxymethylamine Specification

The Methoxymethylamine, with the CAS registry number 1117-97-1, is also known as O,N-Dimethylhydroxylamine. Its EINECS number is 214-255-2. This chemical's molecular formula is C2H7NO and molecular weight is 61.08. What's more, its systematic name is N-Methoxymethanamine.

Physical properties of Methoxymethylamine are: (1)ACD/LogP: 0.13; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.06; (4)ACD/LogD (pH 7.4): 0.13; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 23.82; (8)ACD/KOC (pH 7.4): 27.99; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 21.26 Å2; (13)Index of Refraction: 1.353; (14)Molar Refractivity: 16.655 cm3; (15)Molar Volume: 76.728 cm3; (16)Polarizability: 6.602×10-24cm3; (17)Surface Tension: 18.6 dyne/cm; (18)Density: 0.796 g/cm3; (19)Flash Point: -28.618 °C; (20)Enthalpy of Vaporization: 25.189 kJ/mol; (21)Boiling Point: 2.908 °C at 760 mmHg; (22)Vapour Pressure: 1706.8 mmHg at 25°C.

Preparation: this chemical can be prepared by N,O-dimethyl-hydroxylamine; hydrochloride by distillation. This reaction will need reagent NaOH and solvent dimethylformamide. The yield is about 92%.

Methoxymethylamine can be prepared by N,O-dimethyl-hydroxylamine; hydrochloride by distillation

Uses of Methoxymethylamine: it can be used to produce N-methoxy-N-methyl-a-monohydrohexafluoroisobutyramide at the temperature of 20 °C. It will need solvent diethyl ether with the reaction time of 48 hours. The yield is about 78.1%.

Methoxymethylamine can be used to produce N-methoxy-N-methyl-a-monohydrohexafluoroisobutyramide at the temperature of 20 °C

You can still convert the following datas into molecular structure:
(1)SMILES: O(NC)C
(2)Std. InChI: InChI=1S/C2H7NO/c1-3-4-2/h3H,1-2H3
(3)Std. InChIKey: KRKPYFLIYNGWTE-UHFFFAOYSA-N 

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