Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

Related Products

Hot Products

Name

Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

EINECS 221-615-2
CAS No. 3162-96-7 Density 1.36 g/cm3
PSA 77.38000 LogP 0.19370
Solubility It is soluble in water, acetone, benzene, ethyl ether Melting Point 164-167 °C
Formula C14H18O6 Boiling Point 473 °C at 760 mmHg
Molecular Weight 282.293 Flash Point 239.8 °C
Transport Information N/A Appearance White crystalline solid
Safety 22-24/25-45-36/37/39-27-26 Risk Codes 20/21/22-34
Molecular Structure Molecular Structure of 3162-96-7 (METHYL 4,6-O-BENZYLIDENE-ALPHA-D-GLUCOPYRANOSIDE) Hazard Symbols CorrosiveC
Synonyms

Glucopyranoside,methyl 4,6-O-benzylidene-, a-D- (6CI,7CI,8CI);(+)-(4,6-O-Benzylidene)methyl-a-D-glucopyranoside;α-D-glucopyranoside, methyl 4,6-O-(phenylmethylene)-;

Article Data 192

Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside Specification

The systematic name of this chemical is Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside. With the CAS registry number 3162-96-7 and EINECS registry number 221-615-2, it is also called a-D-Glucopyranoside, methyl4,6-O-(phenylmethylene)-. In addition, the molecular formula is C14H18O6 and the molecular weight is 282.29. It is a kind of white crystalline solid and belongs to the classes of Sugars, Carbohydrates & Glucosides; 13C & 2H Sugars; Biochemistry; Glucose; Glycosides; O-Substituted Sugars; Sugars; Carbohydrates & Derivatives.

Physical properties about this chemical are: (1)ACD/LogP: 0.89; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.89; (4)ACD/LogD (pH 7.4): 0.89; (5)ACD/BCF (pH 5.5): 2.79; (6)ACD/BCF (pH 7.4): 2.79; (7)ACD/KOC (pH 5.5): 72.52; (8)ACD/KOC (pH 7.4): 72.51; (9)#H bond acceptors: 6; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 55.38 Å2; (13)Index of Refraction: 1.586; (14)Molar Refractivity: 69.61 cm3; (15)Molar Volume: 207.3 cm3; (16)Polarizability: 27.59 ×10-24cm3; (17)Surface Tension: 56.4 dyne/cm; (18)Density: 1.36 g/cm3; (19)Flash Point: 239.8 °C; (20)Enthalpy of Vaporization: 77.54 kJ/mol; (21)Boiling Point: 473 °C at 760 mmHg; (22)Vapour Pressure: 9.45E-10 mmHg at 25°C.

Preparation of Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside: it can be prepared by methyl a-D-mannopyranoside and dimethoxymethyl-benzene. The other two products are methyl-[O2,O3;O4,O6-((S,R)-dibenzylidene)-a-D-mannopyranoside] and methyl-[O2,O3;O4,O6-((R,R)-dib. This reaction will need reagent pyridinium p-toluenesulfonate and solvent dimethylformamide. The reaction time is 2 hours at reaction temperature of 80 °C. The yield is about 51%.

Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside can be prepared by methyl a-D-mannopyranoside and dimethoxymethyl-benzene. The other two products are methyl-[O2,O3;O4,O6-((S,R)-dibenzylidene)-a-D-mannopyranoside] and methyl-[O2,O3;O4,O6-((R,R)-dib
Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside can be prepared by methyl a-D-mannopyranoside and dimethoxymethyl-benzene. The other two products are methyl-[O2,O3;O4,O6-((S,R)-dibenzylidene)-a-D-mannopyranoside] and methyl-[O2,O3;O4,O6-((R,R)-dib

Uses of Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside: it can react with N-dichloromethylene-N,N-diethylammonium chloride to get methyl 4,6-O-benzylidene-2-O-(N,N-diethylcarbamoyl)-a-D-mannoside. This reaction will need reagent triethylamine and solvent CH2Cl2. The reaction time is 5 hours at reaction temperature of 25 °C by. The yield is about 90%.

Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside can react with N-dichloromethylene-N,N-diethylammonium chloride to get methyl 4,6-O-benzylidene-2-O-(N,N-diethylcarbamoyl)-a-D-mannoside

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation, in contact with skin and if swallowed. It can cause burns. During using it, wear suitable protective clothing, gloves and eye/face protection and avoid contact with skin and eyes. And you should not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.). What's more, you should take off all contaminated clothing immediately.

You can still convert the following datas into molecular structure:
(1)SMILES: O1C[C@H]3O[C@H](OC)[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1c2ccccc2
(2)InChI: InChI=1/C14H18O6/c1-17-14-11(16)10(15)12-9(19-14)7-18-13(20-12)8-5-3-2-4-6-8/h2-6,9-16H,7H2,1H3/t9-,10-,11-,12-,13-,14+/m1/s1
(3)InChIKey: VVSWDMJYIDBTMV-UQPQVDFHBV

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 3162-96-7