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Cas Database

Name	Potassium gluconate	EINECS	206-074-2
CAS No.	299-27-4	Density	1.73 g/cm3
PSA	141.28000	LogP	-4.82780
Solubility	Soluble in water. (50 mg/ml).	Melting Point	183 °C (dec.)(lit.)
Formula	C₆H₁₁O₇K	Boiling Point	673.6 °C at 760 mmHg
Molecular Weight	234.247	Flash Point	375.2 °C
Transport Information	N/A	Appearance	white to off-white crystalline or granular powder
Safety	24/25	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	N/A
Synonyms	D-Gluconicacid, monopotassium salt (9CI);Gluconic acid, monopotassium salt, D- (8CI);Gluconic acid potassium salt;Gluconsan K;Helshas K;K-IAO;Kalimozan;Kalium-Beta;Kaon;Katorin;Katrin;Potalium;Potasoral;Potassium D-gluconate;Potassuril;Sirokal;Tumil K;	Article Data	3

Potassium gluconate Synthetic route

: 50-99-7
D-glucose

: 299-27-4
potassium gluconate

Conditions

Conditions	Yield
With potassium carbonate; potassium bromide Electrolysis.durch elektrolytische Oxydation;

: 143539-05-3
2,3-Anhydro-6-bromo-6-deoxy-D-mannono-1,4-lactone

: 299-27-4
potassium gluconate

Conditions

Conditions	Yield
With hydrogenchloride; potassium carbonate In water; 4-methyl-2-pentanone for 48h; pH=2 - 7;

: 90-80-2
D-Glucono-1,5-lactone

: 299-27-4
potassium gluconate

Conditions

Conditions	Yield
With potassium hydroxide In water for 2h; Thermodynamic data; Heating;

: 555-31-7
aluminum isopropoxide

: 299-27-4
potassium gluconate

: 152776-71-1
{Al(gluconate)(OH)2}

Conditions

Conditions	Yield
In water gluconate in water acidified with HCl, addn. of Al-compd., heated at 60°C for 3 h; cooled to room temp., addn. of acetone, filtered, redissolved in water, repptd. with ethanol; elem. anal.;	93%

: 299-27-4
potassium gluconate

: potassium 2-dehydro-3-deoxy-D-gluconate

Conditions

Conditions	Yield
With transformed E.coli BL21 In water at 37℃; pH=8.5; Product distribution / selectivity; Microbiological reaction;

: 299-27-4
potassium gluconate

: nickel(II) nitrate

: nickel(II) saccharate trihydrate

Conditions

Conditions	Yield
In water pptn. (25°C, 24 h); collection (filtn.), drying over silica gel (2 weeks); elem. anal.;

: oxovanadium(IV) sulfate

: 299-27-4
potassium gluconate

: [VO(H2O)2(D-gluconate-2H)]

: [(VO(H2O)(D-gluconate-2H))2(μ-OH)]

Conditions

Conditions	Yield
In water synthesized by modified procedure according to Williams, P. A. M. et al., Carbohydr. Res. 329 (2000) 4; concd. solns. V and org. compds. mixed in water at neutral pH; solvent evapd., recrystd.;

: 299-27-4
potassium gluconate

A: 52153-09-0
L-glucono-1,5-lactone

B: 74464-44-1
γ lactone of/the/ l-gluconic acid

Conditions

Conditions	Yield
Stage #1: potassium gluconate With hydrogenchloride In water at 50℃; pH=2.5; Heating / reflux; Stage #2: With triethylamine In water at 20℃; pH=7;

Potassium gluconate Chemical Properties

IUPAC Name: Potassium (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanoate
Empirical Formula: C₆H₁₁KO₇
Molecular Weight: 234.2456
Canonical SMILES: C(C(C(C(C(C(=O)[O-])O)O)O)O)O.[K+]
Isomeric SMILES: C([C@H]([C@H]([C@@H]([C@H](C(=O)[O-])O)O)O)O)O.[K+]
InChI: InChI=1S/C6H12O7.K/c7-1-2(8)3(9)4(10)5(11)6(12)13;/h2-5,7-11H,1H2,(H,12,13);/q;+1/p-1/t2-,3-,4+,5-;/m1./s1
InChIKey: HLCFGWHYROZGBI-JJKGCWMISA-M
EINECS: 206-074-2
Melting Point: 183 °C (dec.)(lit.)
Flash Point: 375.2 °C
Enthalpy of Vaporization: 113.2 kJ/mol
Boiling Point: 673.6 °C at 760 mmHg
Vapour Pressure: 4.95E-21 mmHg at 25 °C
Product Categories: Biochemistry; Glucose; Sugar Acids; Sugars
Classification Code of Potassium gluconate (CAS NO.299-27-4): Drug / Therapeutic Agent; Replenisher [electrolyte]

Potassium gluconate Uses

Potassium gluconate (CAS NO.299-27-4) can be used as a medicinal and potassium supplement agent.

Potassium gluconate Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	2333mg/kg (2333mg/kg)		Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972.
mouse	LD50	oral	9100mg/kg (9100mg/kg)	SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION BEHAVIORAL: SLEEP BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)	Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972.
mouse	LD50	subcutaneous	8190mg/kg (8190mg/kg)		Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972.
rat	LD50	intraperitoneal	2664mg/kg (2664mg/kg)		Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972.
rat	LD50	oral	10380mg/kg (10380mg/kg)	SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION BEHAVIORAL: SLEEP BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)	Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972.
rat	LD50	subcutaneous	9650mg/kg (9650mg/kg)		Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972.

Potassium gluconate Consensus Reports

Reported in EPA TSCA Inventory.

Potassium gluconate Safety Profile

Risk Statements : 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements : 24/25
S24/25:Avoid contact with skin and eyes.
WGK Germany : 1
RTECS : LZ5230000
Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. When heated to decomposition it emits toxic fumes of K₂O.

Potassium gluconate Specification

Potassium gluconate (CAS NO.299-27-4), its Synonyms are D-Gluconic acid, monopotassium salt ; Gluconic acid potassium salt ; Gluconic acid, monopotassium salt ; Gluconsan K ; K-Iao ; KOK ; Kalium Gluconate ; Kalium-beta ; Kaon ; Kaon elixir ; Katorin ; Monopotassium D-gluconate ; Potalium ; Potasoral ; Potassium D-gluconate . It is white to off-white crystalline or granular powder.

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