Dodecanal, oxime

Base Information

• Chemical Name: Dodecanal, oxime
• CAS No.: 13372-76-4
• Molecular Formula: C12H25NO
• Molecular Weight: 199.337
• Mol file: 13372-76-4.mol

Synonyms:Dodecyl aldoxime;DODECANAL, OXIME;BRN 1705588;13372-76-4;3-01-00-02913 (Beilstein Handbook Reference);SCHEMBL1649118;LS-63405

Chemical Property of Dodecanal, oxime

Chemical Property:

• Vapor Pressure: 0.004mmHg at 25°C
• Boiling Point: 259.046°C at 760 mmHg
• Flash Point: 148.816°C
• Density: 0.879g/cm³
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 10
• Exact Mass: 199.193614421
• Heavy Atom Count: 14
• Complexity: 124

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCC=NO
• Isomeric SMILES: CCCCCCCCCCC/C=N/O

Technology Process of Dodecanal, oxime

There total 3 articles about Dodecanal, oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

Dodecanal (112-54-9) → n-dodecanaldoxime (13372-76-4)

Guidance literature:

With hydroxylamine; sodium hydrogencarbonate; In water; at 0 ℃; for 0.166667h;

Reference yield: 65.0%

n-Dodecylamine (124-22-1) → n-dodecanaldoxime (13372-76-4) + didodecyl-diazene dioxide (119135-75-0)

Guidance literature:

With sodium perborate; N,N,N',N'-tetraacetylethylenediamine; sodium hydrogencarbonate; In water; ethyl acetate; for 2.5h; Ambient temperature;

DOI:10.1016/S0040-4039(01)89003-1

Reference yield:

→ n-dodecanaldoxime (13372-76-4)

Guidance literature:

upstream raw materials:

n-Dodecylamine

Dodecanal

Downstream raw materials:

n-Dodecylamine

Dodecanal

3-hydroxy-1,3-diphenyl-2-propen-1-one

undecyl cyanide

Refernces

• 1、 Bhutia, Zigmee T.,Das, Avijit,Biswas, Malabika,Chatterjee, Amrita,Banerjee, Mainak. "7-Oxa-4-thia-1-aza-bicyclo[3.2.1]octane 4,4-Dioxides: Mechanochemical Synthesis by Tandem Michael Addition–1,3-Dipolar Cycloaddition of Aldoximes and Evaluation of Antibacterial Activities". . p. 506 - 514. Retrieved 2018/02/09.
• 2、 Aakeroey, Christer B.,Sinha, Abhijeet S.,Epa, Kanishka N.,Spartz, Christine L.,Desper, John. "A versatile and green mechanochemical route for aldehyde-oxime conversions". supporting information. p. 11289 - 11291,3. Retrieved 2012/12/12.