Technology Process of Stannane, trimethyl(1-methylethenyl)-
There total 9 articles about Stannane, trimethyl(1-methylethenyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
boron trifluoride diethyl etherate; ammonium chloride;
In
dichloromethane;
Ar; -78°C; slow addn. of BF3*Et2O; after 1 h hydrolysed with NH4Cl/H2O at room temp.;; aq. layer extd. with Et2O; combined organic layers dried over Na2SO4; evapd.; chromd. (Al2O3, CH2Cl2).; spectroscopy;;
DOI:10.1016/0022-328X(91)86010-N
- Guidance literature:
-
With
boron trifluoride diethyl etherate; ammonium bromide;
In
dichloromethane;
Ar; -78°C; slow addn. of BF3*Et2O; after 1 h hydrolysed with NH4Br/H2O at room temp.;; aq. layer extd. with Et2O; combined organic layers dried over Na2SO4; evapd.; identified by 1H-, 13C- and 119Sn- spectroscopy;;
DOI:10.1016/0022-328X(91)86010-N
- Guidance literature:
-
With
boron trifluoride diethyl etherate; ammonium chloride;
In
dichloromethane;
Ar; -78°C; slow addn. of BF3*Et2O; after 1 h hydrolysed with NH4Cl/H2O at room temp.;; aq. layer extd. with Et2O; combined organic layers dried over Na2SO4; evapd.; recrystd. from CH2Cl2/ether.; identified by 1H-, 13C- and 119Sn- spectroscopy;;
DOI:10.1016/0022-328X(91)86010-N
