S-benzyl phenylmethanesulfonothioate

Base Information

• Chemical Name: S-benzyl phenylmethanesulfonothioate
• CAS No.: 16601-40-4
• Molecular Formula: C14H14 O2 S2
• Molecular Weight: 278.396
• Mol file: 16601-40-4.mol

Synonyms:a-Toluenesulfonic acid, thio-,S-benzyl ester (6CI,7CI,8CI); Benzyl phenylmethanethiolsulfonate; Benzyl a-toluenethiolsulfonate; NSC 74663

Chemical Property of S-benzyl phenylmethanesulfonothioate

Chemical Property:

• Vapor Pressure: 5.57E-09mmHg at 25°C
• Boiling Point: 482°C at 760 mmHg
• Flash Point: 245.3°C
• Density: 1.277g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-benzyl phenylmethanesulfonothioate

There total 52 articles about S-benzyl phenylmethanesulfonothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

phenylmethanethiol (100-53-8) → S-benzyl phenyl-methanethiosulfonate (16601-40-4)

Guidance literature:

With chlorine; sodium carbonate; In Petroleum ether; for 0.5h; Ambient temperature;

Reference yield: 82.0%

dibenzyl disulphide (150-60-7) → phenylmethylsulphonyl fluoride (329-98-6) + S-benzyl phenyl-methanethiosulfonate (16601-40-4)

Guidance literature:

With water; Selectfluor; In acetonitrile; at 20 ℃; for 0.0333333h;

DOI:10.1016/j.tetlet.2011.03.132

Reference yield: 43.0%

petivericin (16302-98-0) → dibenzyl disulphide (150-60-7) + S-benzyl phenyl-methanethiosulfonate (16601-40-4)

Guidance literature:

With trifluoroacetic acid;

DOI:10.1039/P29800000432

upstream raw materials:

dibenzyl disulphide

benzylthioacetone

dibenzyl sulfide

Dibenzyl sulfoxide

Downstream raw materials:

dibenzyl disulphide

α,α-bis-benzylsulfanyl-deoxybenzoin

N-(4-amino-2-methyl-pyrimidin-5-ylmethyl)-N-(2-benzyldisulfanyl-4-hydroxy-1-methyl-but-1-enyl)-formamide

dibenzyl sulfide

Refernces

• 1、 -. "Preparation method of sulfuryl thioester". Paragraph 0034-0037. . Retrieved 2021/11/10.
• 2、 Kim, Junsu,Park, Sanggil,Kim, Hyungjun,Kim, Jinho. "CuCl2-promoted decomposition of sulfonyl hydrazides for the synthesis of thiosulfonates". . . Retrieved 2020/07/02.