3-FURYLMETHYL ACETATE

Base Information

• Chemical Name: 3-FURYLMETHYL ACETATE
• CAS No.: 30614-67-6
• Molecular Formula: C7H8O3
• Molecular Weight: 140.139
• Hs Code.: 2932190090
• Mol file: 30614-67-6.mol

Synonyms:3-Furylmethyl acetate;3-acetoxymethylfuran;

Chemical Property of 3-FURYLMETHYL ACETATE

Chemical Property:

• Vapor Pressure: 0.893mmHg at 25°C
• Boiling Point: 180.5oC at 760 mmHg
• Flash Point: 72.2oC
• PSA: 39.44000
• Density: 1.12g/cm3
• LogP: 1.34270

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-FURYLMETHYL ACETATE

There total 3 articles about 3-FURYLMETHYL ACETATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

ethyl 3-furancarboxylate (614-98-2) → furan-3-methanol (4412-91-3) + furan-3-ylmethyl acetate (30614-67-6)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 0.75h; Inert atmosphere;

DOI:10.1016/j.tet.2012.09.070 DOI:10.1016/j.tet.2012.09.070

Reference yield:

3-Furoic acid (488-93-7) → furan-3-methanol (4412-91-3) + furan-3-ylmethyl acetate (30614-67-6)

Guidance literature:

Multi-step reaction with 3 steps

1: thionyl chloride / 4 h / 20 °C / Inert atmosphere; Reflux

2: 1 h / Inert atmosphere; Reflux

3: lithium aluminium tetrahydride / diethyl ether / 0.75 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; thionyl chloride; In diethyl ether;

DOI:10.1016/j.tet.2012.09.070 DOI:10.1016/j.tet.2012.09.070

Reference yield:

furan-3-carbonyl chloride (26214-65-3) → furan-3-methanol (4412-91-3) + furan-3-ylmethyl acetate (30614-67-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 1 h / Inert atmosphere; Reflux

2: lithium aluminium tetrahydride / diethyl ether / 0.75 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1016/j.tet.2012.09.070 DOI:10.1016/j.tet.2012.09.070

upstream raw materials:

3-Furoic acid

ethyl 3-furancarboxylate

furan-3-carbonyl chloride

Downstream raw materials:

C₁₉H₁₉NO₆

furan-3-methanol

Refernces

• 1、 Monta?a, ángel M.,Grima, Pedro M.,Castellví, María,Batalla, Consuelo,Font-Bardia, Mercè. "Cycloaddition of C-3 substituted furans. Stereoselectivity induced by coordination effects". . p. 9982 - 9998. Retrieved 2013/01/14.