[(η5-C5H5)(CO)MoCl(κ2-MeN[P(OPh)2]2)]*CH2Cl2

Base Information

• Chemical Name: [(η5-C5H5)(CO)MoCl(κ2-MeN[P(OPh)2]2)]*CH2Cl2
• CAS No.: 849364-73-4
• Molecular Formula: CH₂Cl₂*C₃₁H₂₈ClMoNO₅P₂
• Molecular Weight: 772.84
• Mol file: 849364-73-4.mol

Synonyms:

Chemical Property of [(η5-C5H5)(CO)MoCl(κ2-MeN[P(OPh)2]2)]*CH2Cl2

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

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Useful:

Technology Process of [(η5-C5H5)(CO)MoCl(κ2-MeN[P(OPh)2]2)]*CH2Cl2

There total 1 articles about [(η5-C5H5)(CO)MoCl(κ2-MeN[P(OPh)2]2)]*CH2Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.2%

cyclopentadienylmolybdenum tricarbonyl dimer + dichloromethane (75-09-2) + [Pd2Cl2(μ-MeN[P(OPh)2]2)2] (126032-76-6) → [(η5-C5H5)Mo(μ-CO)(μ-Cl)(μ-MeN[P(OC6H5)2]2)PdCl] (849364-72-3) + [(η5-C5H5)(CO)MoCl(κ2-MeN[P(OPh)2]2)]*CH2Cl2 (849364-73-4) + [(η5-C5H5)(CO)Mo(μ-MeN[P(OPh)2]2)2PdCl] + [(η5-C5H5)Mo(μ3-CO)2(μ-MeN[P(OC6H5)2]2)2Pd2Cl]*0.5CH2Cl2

Guidance literature:

In benzene; under N2 atm. using Schlenk techniques; soln. of Pd complex and Mo2(C5H5)2(CO)6 in C6H6 heated under reflux for 3 ds using an oil bath maintained at 90°C; mixt. cooled to 25°C; solvent removed (vac.); residue dissolved in CH2Cl2; subjected to columnchromy. using silica gel (petrol-Et2O (4:1, 2:1, 1:1 v/v), Et2O-CH2Cl2 (4:1) as eluents); solvent removed from each fraction in vac.; elem. ana l.;

DOI:10.1016/j.jorganchem.2004.10.053

upstream raw materials:

dichloromethane

[Pd2Cl2(μ-MeN[P(OPh)2]2)2]

Refernces