2-Chloro-1-octene

Base Information

• Chemical Name: 2-Chloro-1-octene
• CAS No.: 31283-43-9
• Molecular Formula: C8H15Cl
• Molecular Weight: 146.66
• Hs Code.: 2903299090
• Mol file: 31283-43-9.mol

Synonyms:2-chloro-oct-1-ene;2-Chlor-octylen;2-Chlor-oct-1-en;1-Octene, 2-chloro-;2-chloro-1-octene;2-Chlor-1-octen;

Chemical Property of 2-Chloro-1-octene

Chemical Property:

• Vapor Pressure: 2.086mmHg at 25°C
• Refractive Index: 1.4339 (estimate)
• Boiling Point: 168.999oC at 760 mmHg
• Flash Point: 49.378oC
• PSA: 0.00000
• Density: 0.879g/cm3
• LogP: 3.70930

Purity/Quality:

95% ^*data from raw suppliers

2-chloro-1-octene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Chloro-1-octene

There total 5 articles about 2-Chloro-1-octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

n-octyne (629-05-0) + ethylene glycol (107-21-1) → 2-methyl-2-hexyl-1,3-dioxolane (937-94-0) + 2-chloro-oct-1-ene (31283-43-9)

Guidance literature:

With triisopropyl phosphite; zirconium(IV) chloride; [Ir(1,5-cyclooctadiene)2]PF₆; In 1,4-dioxane; at 100 ℃; for 15h;

DOI:10.1016/j.tet.2005.12.010

Reference yield: 26.0%

hexyl-methyl-ketone (111-13-7) → 2,2-dichloro-octane (73642-95-2) + 2-chloro-oct-1-ene (31283-43-9) + (Z)-2-Chlor-2-octen (90202-21-4) + (E)-2-Chlor-2-octen (57024-91-6)

Guidance literature:

With phosphorus pentachloride; In benzene; for 12h; Yields of byproduct given; Ambient temperature;

Reference yield: 20.0%

n-octyne (629-05-0) → 2-chloro-oct-1-ene (31283-43-9) + hexyl-methyl-ketone (111-13-7)

Guidance literature:

With octane; water; iron(III) chloride; In dichloromethane; at 65 ℃; for 24h;

DOI:10.1016/0022-328X(96)06294-8

upstream raw materials:

Phenylselenyl chloride

oct-1-ene

1,2-dichlorooctane

hexyl-methyl-ketone

Downstream raw materials:

N-(4-methoxyphenyl)-2-aminooctane

2,2-Difluor-octan

Refernces

• 1、 Damiano, Jean Pierre,Postel, Michele. "FeCl3-H2O: A specific system for arylacetylene hydration". . p. 303 - 305. Retrieved 2007/10/03.
• 2、 Dehmlow, Eckehard V.,Thieser, Rainer,Sasson, Yoel,Neumann, Ronny. "DIOLS AS EFFECTIVE COCATALYSTS IN THE PHASE TRANSFER CATALYZED PREPARATION OF 1-ALKYNES FROM 1,2-DIHALIDES". . p. 3569 - 3574. Retrieved 2007/10/02.