(-)-Bromochlorofluoromethane

Base Information

• Chemical Name: (-)-Bromochlorofluoromethane
• CAS No.: 31747-37-2
• Molecular Formula: CHBrClF
• Molecular Weight: 147.37400
• Hs Code.: 2903799090
• Mol file: 31747-37-2.mol

Synonyms:(-)-Bromochlorofluoromethane;Methane,bromochlorofluoro-,(1R)-;(R)-bromo-chloro-fluoromethane;

Chemical Property of (-)-Bromochlorofluoromethane

Chemical Property:

• PSA: 0.00000
• LogP: 1.87320

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (-)-Bromochlorofluoromethane

There total 5 articles about (-)-Bromochlorofluoromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Fluorochlorobromoacetic acid (354-03-0) → (+)-Bromchlorfluormethan (593-98-6,22611-58-1,31747-37-2,88987-26-2,132695-86-4,136777-47-4) + (-)-Bromochlorofluoromethane (593-98-6,22611-58-1,31747-37-2,88987-26-2,132695-86-4,136777-47-4)

Guidance literature:

With ethylene glycol; strychnidin-10-one; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 2.) 100-120 deg C;

DOI:10.1021/ja00204a029

Reference yield:

Fluorochlorobromoacetic acid (354-03-0) → (+)-Bromchlorfluormethan (593-98-6,22611-58-1,31747-37-2,88987-26-2,132695-86-4,136777-47-4) + (-)-Bromochlorofluoromethane (593-98-6,22611-58-1,31747-37-2,88987-26-2,132695-86-4,136777-47-4)

Guidance literature:

With ethylene glycol; strychnidin-10-one; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 2.) 100-120 deg C;

DOI:10.1021/ja00204a029

Reference yield:

(+)-1-bromo-1-chloro-1-fluoro-propan-2-one (421-34-1,22611-59-2,22611-60-5) → (+)-Bromchlorfluormethan (593-98-6,22611-58-1,31747-37-2,88987-26-2,132695-86-4,136777-47-4)

Guidance literature:

With potassium hydroxide;

DOI:10.1039/c29690000016 DOI:10.1039/j39710001013

upstream raw materials:

(+)-1-bromo-1-chloro-1-fluoro-propan-2-one

Fluorochlorobromoacetic acid

(-)-1-bromo-1-chloro-1-fluoro-propan-2-one

Refernces

• 1、 Doyle, Thomas R.,Vogl, Otto. "Bromochlorofluoromethane and Deuteriobromochlorofluoromethane of High Optical Purity". . p. 8510 - 8511. Retrieved 2007/10/02.