CID 6085737

Base Information

• Chemical Name: CID 6085737
• CAS No.: 32188-71-9
• Molecular Formula: C14H8Cl4N2
• Molecular Weight: 346.043
• Hs Code.: 2928000090
• European Community (EC) Number: 688-716-5
• Nikkaji Number: J308.273C
• Mol file: 32188-71-9.mol

Synonyms:32188-71-9;2,6-Dichlorobenzaldehyde azine;(Z)-1-(2,6-dichlorophenyl)-N-[(Z)-(2,6-dichlorophenyl)methylideneamino]methanimine

Chemical Property of CID 6085737

Chemical Property:

• Boiling Point: 438.0±45.0 °C(Predicted)
• PKA: 4.33±0.50(Predicted)
• PSA: 24.72000
• Density: 1.39±0.1 g/cm3(Predicted)
• LogP: 5.75320
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 345.941209
• Heavy Atom Count: 20
• Complexity: 307

Purity/Quality:

98.5% ^*data from raw suppliers

4-ETHOXYBENZALDEHYDE AZINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=C(C(=C1)Cl)C=NN=CC2=C(C=CC=C2Cl)Cl)Cl
• Isomeric SMILES: C1=CC(=C(C(=C1)Cl)/C=N\N=C/C2=C(C=CC=C2Cl)Cl)Cl

Technology Process of CID 6085737

There total 7 articles about CID 6085737 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

tetrachloromethane (56-23-5) + 2,6-dichlorobenzaldehyde hydrazone (59714-30-6) → 2,6-dichlorobenzaldehyde (2,6-dichlorobenzylidene)hydrazone (32188-71-9) + 1-(2,2-dichlorovinyl)-2,6-dichlorobenzene (5281-25-4)

Guidance literature:

With copper(I) chloride; ammonium hydroxide; In dimethyl sulfoxide; at 20 ℃; for 4h;

DOI:10.1016/S0040-4020(00)00606-2

Reference yield: 74.0%

2,6-dichlorobenzaldehyde (83-38-5) → 2,6-Dichlorbenzaldehyd-azin (32188-71-9)

Guidance literature:

With hydrazine hydrate; In ethanol;

DOI:10.1016/j.jorganchem.2004.04.049

Reference yield: 68.0%

trichlorofluoromethane (75-69-4) + 2,6-dichlorobenzaldehyde (83-38-5) → 2,6-dichlorobenzaldehyde (2,6-dichlorobenzylidene)hydrazone (32188-71-9) + 1,3-dichloro-2-(2-chloro-2-fluorovinyl)benzene

Guidance literature:

With hydrazine hydrate; ethylenediamine; copper(l) chloride; In ethanol; at 20 ℃; for 24h; 4;

DOI:10.1002/ejoc.200390033

upstream raw materials:

2,6-dichlorobenzaldehyde

tetrachloromethane

2,6-dichlorobenzaldehyde hydrazone

trichlorofluoromethane

Downstream raw materials:

2,6-dichlorobenzaldehyde hydrazone

2,6-dichlorotoluene

chlorotris(trimethylphosphane)cobalt(I)

(C₆H₃ClCHNNCHC₆H₃Cl₂)CoCl(CH₃)(P(CH₃)3)2

Refernces

• 1、 Garcia, Marco A.,Garcia-Munoz, Angel,Pena, Josue A.,Trujillo-Reyes, Jessica,Morales-Luckie, Raul A.,Avalos-Borja, Miguel,Vilchis-Nestor, Alfredo R.,Sanchez-Mendieta, Victor,Corona, David,Cuevas-Yanez, Erick. "Carbenoid Etherifications catalyzed by "green" silver nanoparticles and iron-copper nanoparticles". experimental part. p. 2 - 6. Retrieved 2012/07/16.
• 2、 Nenajdenko, Valentine G.,Shastin, Alexey V.,Korotchenko, Vasily N.,Varseev, Georgy N.,Balenkova, Elisabeth S.. "A novel approach to 2-chloro-2-fluorostyrenes". . p. 302 - 308. Retrieved 2007/10/03.