Benzene, (butyltelluro)-

Base Information

• Chemical Name: Benzene, (butyltelluro)-
• CAS No.: 32343-98-9
• Molecular Formula: C10H14Te
• Molecular Weight: 261.821
• Mol file: 32343-98-9.mol

Synonyms:

Chemical Property of Benzene, (butyltelluro)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, (butyltelluro)-

There total 18 articles about Benzene, (butyltelluro)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

n-butyllithium (109-72-8,29786-93-4) + iodobenzene (591-50-4) → n-butyl(phenyl)tellane (32343-98-9)

Guidance literature:

n-butyllithium; With tellurium; In tetrahydrofuran; hexane; at 20 ℃; for 0.0833333h; Inert atmosphere;

iodobenzene; With copper(l) iodide; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; for 6h; Inert atmosphere; Heating;

DOI:10.1016/j.tet.2011.09.014

Reference yield: 85.0%

1-bromo-butane (109-65-9) + phenylmagnesium bromide → n-butyl(phenyl)tellane (32343-98-9)

Guidance literature:

phenylmagnesium bromide; With tellurium; In tetrahydrofuran; at 20 ℃; for 2h;

1-bromo-butane; In tetrahydrofuran; at -20 - 20 ℃;

DOI:10.1021/jo052061r

Reference yield: 84.0%

1-bromo-butane (109-65-9) + diphenyl ditelluride (32294-60-3) → n-butyl(phenyl)tellane (32343-98-9)

Guidance literature:

diphenyl ditelluride; With bis(η5-cyclopentadienyl)titanium hydride; In tetrahydrofuran; at 0 ℃; for 0.5h;

1-bromo-butane; With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; at 25 - 30 ℃; for 3h;

DOI:10.1080/00397910008087163

upstream raw materials:

1-bromo-butane

diphenyl ditelluride

n-butyllithium

cyclohexenone

Downstream raw materials:

n-Butyl-phenyltelluriumdibromid

n-Butyl-phenyltelluriumdijodid

Pt(C₆H₅)(C₄H₉Te)(P(C₂H₅)3)2

Pt(C₄H₉)(C₆H₅Te)(P(C₂H₅)3)2

Refernces

• 1、 Taniguchi, Nobukazu. "Convenient synthesis of unsymmetrical organochalcogenides using organoboronic acids with dichalcogenides via cleavage of the S-S, Se-Se, or Te-Te bond by a copper catalyst". . p. 1241 - 1245. Retrieved 2007/10/03.
• 2、 Nishiyama, Yutaka,Okada, Mitsuo,Nishino, Toshiki,Sonoda, Noboru. "A new method for the synthesis of organotellurium compounds by the use of reductive cleavage of the tellurium-tellurium bond with lanthanum metal". . p. 341 - 343. Retrieved 2007/10/03.