4,7-Dithiadecane

Base Information

• Chemical Name: 4,7-Dithiadecane
• CAS No.: 22037-97-4
• Molecular Formula: C8H18S2
• Molecular Weight: 178.3585
• European Community (EC) Number: 654-689-3
• NSC Number: 163281
• DSSTox Substance ID: DTXSID8021698
• Nikkaji Number: J481.543B
• Wikidata: Q81983858
• Mol file: 22037-97-4.mol

Synonyms:4,7-dithiadecane;22037-97-4;propane, 1,1'-[1,2-ethanediylbis(thio)]bis-;NSC163281;1,1'-[ethane-1,2-diylbis(thio)]dipropane;1,2-Bis(propylthio)ethane;SCHEMBL778049;DTXSID8021698;AKOS024332229;1-{[2-(propylthio)ethyl]thio}propane;NSC-163281

Chemical Property of 4,7-Dithiadecane

Chemical Property:

• Vapor Pressure: 0.0258mmHg at 25°C
• Boiling Point: 255.7°C at 760 mmHg
• Flash Point: 101.6°C
• Density: 0.946g/cm³
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 178.08499292
• Heavy Atom Count: 10
• Complexity: 47.2

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCSCCSCCC

Technology Process of 4,7-Dithiadecane

There total 6 articles about 4,7-Dithiadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

1-thiopropane (107-03-9) + ethylene dibromide (106-93-4) → 4,7-dithiadecane (22037-97-4)

Guidance literature:

1-thiopropane; With potassium hydroxide; hydrazine hydrate; for 1h;

ethylene dibromide; at 50 ℃; for 2h;

DOI:10.1023/A:1022540002086

Reference yield: 70.0%

1,2-dichloro-ethane (107-06-2,52399-93-6) + Dipropyl disulfide (629-19-6) → 4,7-dithiadecane (22037-97-4)

Guidance literature:

Dipropyl disulfide; With sodium hydroxide; hydrazine hydrate; at 90 ℃;

1,2-dichloro-ethane; at 50 ℃; for 2h;

DOI:10.1023/A:1015397313038

Reference yield: 36.0%

1-thiopropane (107-03-9) + 1,2-dichloro-ethane (107-06-2,52399-93-6) → 4,7-dithiadecane (22037-97-4) + 2-chloroethyl-n-propylsulfide (4303-42-8)

Guidance literature:

1-thiopropane; With potassium hydroxide; hydrazine hydrate; for 1h;

1,2-dichloro-ethane; at 50 ℃; for 2h;

DOI:10.1023/A:1022540002086

upstream raw materials:

1-thiopropane

acetylene

1-Chloropropane

diethyl ethylenedixanthate

Refernces

• 1、 Russavskaya,Korchevin,Alekminskaya,Sukhomazova,Levanova,Deryagina. "New preparative procedure for the synthesis of chloroalkyl sulfides". . p. 1445 - 1448. Retrieved 2007/10/03.