1-Butyl-4-methylpyridinium tetrafluoroborate

Base Information

• Chemical Name: 1-Butyl-4-methylpyridinium tetrafluoroborate
• CAS No.: 343952-33-0
• Molecular Formula: C10H16N.BF4
• Molecular Weight: 237.04500
• Hs Code.: 2933399090
• European Community (EC) Number: 629-543-7
• ChEMBL ID: CHEMBL3184234
• DSSTox Substance ID: DTXSID1049275
• Mol file: 343952-33-0.mol

Synonyms:1-butyl-4-methylpyridinium tetrafluoroborate

Chemical Property of 1-Butyl-4-methylpyridinium tetrafluoroborate

Chemical Property:

• Melting Point: 30℃
• Refractive Index: n20/D 1.4
• PSA: 3.88000
• Density: 1.2
• LogP: 3.38260
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 237.1311923
• Heavy Atom Count: 16
• Complexity: 112

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Butyl-4-methylpyridinium Tetrafluoroborate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-36/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [B-](F)(F)(F)F.CCCC[N+]1=CC=C(C=C1)C
• Uses: 4MBPBF4 has been used in the preparation of the SWNT-polymer composite films to improve the dispersion of SWNTs and conductivity of the composites (SWNT= singlewalled carbon nanotubes). The use of 4MBPBF4 as a reaction media during derivatization of dimethyl sulfate with dibenzazepine, accelerates the rate of the reaction. It can also be used to modify carbon paste electrode, which leads to high sensitivity, selectivity and low detection limit for both potassium ferricyanide and dopamine by cyclic voltammetric technique.

Technology Process of 1-Butyl-4-methylpyridinium tetrafluoroborate

There total 6 articles about 1-Butyl-4-methylpyridinium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-n-butyl-4-methylpyridinium chloride (112400-86-9) → 4-methyl-N-butylpyridinium tetrafluoroborate (343952-33-0)

Guidance literature:

With tetrafluoroboric acid; In water; at 20 ℃; for 0.333333h;

Reference yield: 98.0%

1-butyl-4-methylpyridin-1-ium iodide (32353-64-3) → 4-methyl-N-butylpyridinium tetrafluoroborate (343952-33-0)

Guidance literature:

With Amberlyst A-26 (BF₄^- form); In methanol;

DOI:10.1039/c0cc05350c

Reference yield: 84.0%

picoline (108-89-4) + n-Butyl chloride (109-69-3) → 4-methyl-N-butylpyridinium tetrafluoroborate (343952-33-0)

Guidance literature:

With sodium tetrafluoroborate; at 70 ℃; for 336h;

upstream raw materials:

picoline

n-Butyl chloride

1-n-butyl-4-methylpyridinium chloride

1-butyl-4-methylpyridin-1-ium iodide

Refernces

• 1、 Ceron, Miguel A.,Guzman-Lucero, Diego J.,Palomeque, Jorge F.,Martinez-Palou, Rafael. "Parallel microwave-assisted synthesis of ionic liquids and screening for denitrogenation of straight-run diesel feed by liquid-liquid extraction". experimental part. p. 427 - 432. Retrieved 2012/07/01.
• 2、 Dos Santos Castro, Kelly L.,De Lima, Paulo G.,E Miranda, Leandro S.M.,De Souza, Rodrigo O.M.A.. "Microwave assisted Suzuki reaction in N-butylpyridinium salts/water systems". supporting information; experimental part. p. 4168 - 4171. Retrieved 2011/09/19.