Benzene, 1,1'-(1,2-diethyl-1,2-dimethyl-1,2-ethanediyl)bis[4-nitro-

Base Information

• Chemical Name: Benzene, 1,1'-(1,2-diethyl-1,2-dimethyl-1,2-ethanediyl)bis[4-nitro-
• CAS No.: 345651-60-7
• Molecular Formula: C20H24N2O4
• Molecular Weight: 356.422
• Mol file: 345651-60-7.mol

Synonyms:

Chemical Property of Benzene, 1,1'-(1,2-diethyl-1,2-dimethyl-1,2-ethanediyl)bis[4-nitro-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzene, 1,1'-(1,2-diethyl-1,2-dimethyl-1,2-ethanediyl)bis[4-nitro-

There total 1 articles about Benzene, 1,1'-(1,2-diethyl-1,2-dimethyl-1,2-ethanediyl)bis[4-nitro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4-dimethyl-3,4-diphenylhexane (10192-93-5) → meso-3,4-dimethyl-3,4-bis(4'-nitrophenyl)hexane (345651-60-7)

Guidance literature:

With nitric acid; In acetic anhydride;

DOI:10.1021/jo00313a021

Reference yield:

meso-3,4-dimethyl-3,4-bis(4'-nitrophenyl)hexane (345651-60-7) → meso-3,4-dimethyl-3,4-bis(4'-aminophenyl)hexane (130379-07-6)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethyl acetate; under 3040 Torr;

DOI:10.1021/jo00313a021

Reference yield:

meso-3,4-dimethyl-3,4-bis(4'-nitrophenyl)hexane (345651-60-7) → meso-3,4-dimethyl-3,4-bis(4'-diazoniophenyl)hexane ditetrafluoroborate salt (130379-09-8)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂ / 10percent Pd/C / ethyl acetate / 3040 Torr

2: boron trifluoride etherate, tert-butyl nitrite / tetrahydrofuran; CH₂Cl₂

With tert.-butylnitrite; boron trifluoride diethyl etherate; hydrogen; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; ethyl acetate;

DOI:10.1021/jo00313a021

upstream raw materials:

3,4-dimethyl-3,4-diphenylhexane

Downstream raw materials:

meso-3,4-dimethyl-3,4-bis(4'-aminophenyl)hexane

meso-3,4-dimethyl-3,4 bis(4'-methoxyphenyl)hexane

erythro-3,4-dimethyl-3-(4'-methoxyphenyl)-4-phenylhexane

meso-3,4-dimethyl-3,4-bis(4'-diazoniophenyl)hexane ditetrafluoroborate salt

Refernces