[B₂O((S)-VAPOL^(2-))(phenoxy)2]

Base Information

• Chemical Name: [B₂O((S)-VAPOL^(2-))(phenoxy)2]
• CAS No.: 1037075-02-7
• Molecular Formula: C₅₂H₃₄B₂O₅
• Molecular Weight: 760.461
• Mol file: 1037075-02-7.mol

Synonyms:

Chemical Property of [B₂O((S)-VAPOL^(2-))(phenoxy)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [B₂O((S)-VAPOL^(2-))(phenoxy)2]

There total 3 articles about [B₂O((S)-VAPOL^(2-))(phenoxy)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-VAPOL (147702-15-6,147702-16-7,200810-26-0) + triphenylborane (1095-03-0) → [B((S)-VAPOL(2-))(phenoxy)] (1037075-04-9) + [B2O((S)-VAPOL(2-))(phenoxy)2] (1037075-02-7)

Guidance literature:

In toluene; heating biphenanthrol deriv. with 3 equiv. of borate deriv. in toluene at 80°C for 1 h; drying in vac. for 0.5 h, NMR;

DOI:10.1021/ja1070224

Reference yield:

(S)-VAPOL (147702-15-6,147702-16-7,200810-26-0) + N-phenylmethylidene-1,1-bis(4-methoxy-3,5-dimethylphenyl)methylamine (1072879-63-0) + triphenylborane (1095-03-0) + water (7732-18-5) → [B((S)-VAPOL(2-))(phenoxy)] (1037075-04-9) + [B2O((S)-VAPOL(2-))(phenoxy)2] (1037075-02-7) + [PhCHNH(tetra-methyldianisylmethyl)][B3O3((S)-VAPOL(-2H))(phenoxy)2]*0.5CHCl3*1.5CH2Cl2

Guidance literature:

In chloroform-d1; byproducts: C6H5CHO; addn. of 2 equiv. of imine deriv. to mixt. of 1 equiv. of biphenanthrol deriv. with 3 equiv. of borate deriv. in CDCl3 at 25°C, keeping for 10 min; NMR monitoring;

DOI:10.1021/ja1070224

Reference yield:

(S)-VAPOL (147702-15-6,147702-16-7,200810-26-0) + triphenylborane (1095-03-0) → [B2O((S)-VAPOL(2-))(phenoxy)2] (1037075-02-7)

Guidance literature:

In chloroform-d1; reaction of biphenanthrol deriv. with 3 equiv. of borate deriv. in CDCl3at 25°C for 24 h; NMR monitoring;

DOI:10.1021/ja1070224

upstream raw materials:

(S)-VAPOL

N-phenylmethylidene-1,1-bis(4-methoxy-3,5-dimethylphenyl)methylamine

triphenylborane

water

Refernces