Lithium, pentyl-

Base Information

• Chemical Name: Lithium, pentyl-
• CAS No.: 3525-31-3
• Molecular Formula: C5H11Li
• Molecular Weight: 78.0833
• Hs Code.: 2931900090
• European Community (EC) Number: 628-696-7
• DSSTox Substance ID: DTXSID20436584
• Mol file: 3525-31-3.mol

Synonyms:Lithium, pentyl-;lithium;pentane;3525-31-3;Lithium Pentane;DTXSID20436584

Chemical Property of Lithium, pentyl-

Chemical Property:

• PSA: 0.00000
• Density: 0.708 g/mL at 25 °C
• LogP: 2.01070
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 78.10207879
• Heavy Atom Count: 6
• Complexity: 13.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

PENTYLLITHIUM SOLUTION 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,T
• Statements: 45-46-11-14-17-35-65
• Safety Statements: 53-16-26-36/37/39-45-62

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Li+].CCCC[CH2-]

Technology Process of Lithium, pentyl-

There total 4 articles about Lithium, pentyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromopentane (110-53-2) → n-pentyl lithium (3525-31-3)

Guidance literature:

With diethyl ether; lithium; at -10 - 10 ℃;

DOI:10.1021/ja01172a510

Reference yield:

1-Chloropentane (543-59-9) → n-pentyl lithium (3525-31-3)

Guidance literature:

With lithium; Petroleum ether;

Reference yield:

amyl iodide (628-17-1) → n-pentyl lithium (3525-31-3)

Guidance literature:

With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 1h; Schlenk technique;

DOI:10.1039/c7cc09801d

upstream raw materials:

1-Chloropentane

1-Bromopentane

amyl iodide

Downstream raw materials:

decane

3,4-dimethylhexane

3-methyl-octane

tri(n-pentyl)silane

Refernces

• 1、 Zwanenburg, Binne,Volkers, Andries A.,Klunder, Antonius J. H.. "Use of flash vacuum thermolysis in a stereocontrolled synthesis of optically active alkyl-substituted cyclopentenones with fragrant properties". . p. 1234 - 1242. Retrieved 2014/10/16.
• 2、 -. "Method for producing alkyl-bridged ligand systems and transition metal compounds". . . Retrieved 2008/06/13.