7-Quinolinecarboxaldehyde, 8-hydroxy-5-(phenylazo)-

Base Information

• Chemical Name: 7-Quinolinecarboxaldehyde, 8-hydroxy-5-(phenylazo)-
• CAS No.: 361440-80-4
• Molecular Formula: C16H11N3O2
• Molecular Weight: 277.282
• Mol file: 361440-80-4.mol

Synonyms:

Chemical Property of 7-Quinolinecarboxaldehyde, 8-hydroxy-5-(phenylazo)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-Quinolinecarboxaldehyde, 8-hydroxy-5-(phenylazo)-

There total 1 articles about 7-Quinolinecarboxaldehyde, 8-hydroxy-5-(phenylazo)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

8-hydroxy-7-quinolinecarboxaldehyde (5683-78-3) + aniline (62-53-3) → 5-phenyldiazo-8-hydroxy-7-quinolinecarboxaldehyde (361440-80-4)

Guidance literature:

aniline; With hydrogenchloride; sodium nitrite;

8-hydroxy-7-quinolinecarboxaldehyde; In ethanol; alkaline aq. solution;

DOI:10.1248/cpb.49.1308

Reference yield:

4-amino-2,3-dimethyl-1-phenylpyrazolin-5-one (83-07-8) + 5-phenyldiazo-8-hydroxy-7-quinolinecarboxaldehyde (361440-80-4) → 4-{[5-(phenylazo)-8-hydroxyquinolin-7-ylmethylene]amino}-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one

Guidance literature:

In ethanol; for 4h; Reflux;

DOI:10.1007/s11164-016-2474-2

Reference yield:

uranyl(VI) acetate dihydrate + 5-phenyldiazo-8-hydroxy-7-quinolinecarboxaldehyde (361440-80-4) → UO2(OCHC9H4N(O)N2C6H5)2 + UO2(OCHC9H4N(O)N2C6H5)2

Guidance literature:

In ethanol; soln. of UO2 salt in EtOH added to soln. of ligand (molar ratio 1:2) in EtOH; stirred at room temp. for 1 h; filtered; solid washed with water and Et2O; air dried; elem. anal.; mixt. of monomeric and polymeric forms obtained, total yield 75%;

DOI:10.1016/S1386-1425(01)00398-5

upstream raw materials:

8-hydroxy-7-quinolinecarboxaldehyde

aniline

Refernces

• 1、 El-Sonbati,Abou-Dobara,Diab,El-Bindary,Nozha. "Synthesis, characterization, antimicrobial activity and ultrastructure of the affected bacteria of new quinoline compounds". . p. 6449 - 6481. Retrieved 2016/07/06.
• 2、 El-Sonbati,El-Bindary,Shoair,Younes. "Stereochemistry of new nitrogen containing heterocyclic aldehyde. VII. Potentiometric, conductometric and thermodynamic studies of novel quinoline azodyes and their metal complexes with some transition metals". . p. 1308 - 1313. Retrieved 2007/10/03.