Octadecanoic acid, 9,10-dihydroxy-, methyl ester, (9R,10R)-rel-

Base Information

• Chemical Name: Octadecanoic acid, 9,10-dihydroxy-, methyl ester, (9R,10R)-rel-
• CAS No.: 3639-31-4
• Molecular Formula: C₁₉H₃₈O₄
• Molecular Weight: 330.508
• Mol file: 3639-31-4.mol

Synonyms:METHYL DL-THREO-9,10-DIHYDROXYSTEARATE;

Chemical Property of Octadecanoic acid, 9,10-dihydroxy-, methyl ester, (9R,10R)-rel-

Chemical Property:

• PSA: 66.76000
• LogP: 4.36250

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Octadecanoic acid, 9,10-dihydroxy-, methyl ester, (9R,10R)-rel-

There total 22 articles about Octadecanoic acid, 9,10-dihydroxy-, methyl ester, (9R,10R)-rel- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Methyl oleate (112-62-9) → erythro-9,10-dihydroxyoctadecanoic acid methyl ester (1115-01-1,3639-30-3,3639-31-4,38172-86-0,41757-66-8,79815-14-8,95975-76-1)

Guidance literature:

With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In water; acetone; tert-butyl alcohol; at 20 ℃; for 24h;

DOI:10.1002/chem.201500096

Reference yield: 90.0%

methyl (9E)-octadec-9-enoate (2462-84-2) → threo-9,10-dihydroxyoctadecanoic acid methyl ester (1115-01-1,3639-30-3,3639-31-4,38172-86-0,41757-66-8,79815-14-8,95975-76-1)

Guidance literature:

With cethyltrimethylammonium permanganate; In dichloromethane; at 20 ℃; for 100h;

DOI:10.1021/jf400577k

Reference yield:

Methyl oleate (112-62-9) → threo-9,10-dihydroxyoctadecanoic acid methyl ester (1115-01-1,3639-30-3,3639-31-4,38172-86-0,41757-66-8,79815-14-8,95975-76-1) + erythro-9,10-dihydroxyoctadecanoic acid methyl ester (1115-01-1,3639-30-3,3639-31-4,38172-86-0,41757-66-8,79815-14-8,95975-76-1)

Guidance literature:

With air; cobalt(II) oleate; at 65 ℃;

upstream raw materials:

methanol

threo-9,10-dihydroxyoctadecanoic acid

Methyl oleate

octadec-9-enoic acid methyl ester

Downstream raw materials:

(+/-)-8-(5c-octyl-2ξ-phenyl-[1,3]dioxolan-4ρ!-yl)-octanoic acid methyl ester

nonanoic acid

azelaic monomethyl ester

linoleic acid methyl ester

Refernces

• 1、 Zhang, Mohan,Selvakumar, Sermadurai,Zhang, Xinran,Sibi, Mukund P.,Weiss, Richard G.. "Structural and solubility parameter correlations of gelation abilities for dihydroxylated derivatives of long-Chain, naturally occurring fatty acids". supporting information. p. 8530 - 8543. Retrieved 2015/06/02.
• 2、 Piazza, George J.,Nunz, Alberto,Foglia, Thomas A.. "Hydrolysis of Mono- and Diepoxyoctadecanoates by Alumina". . p. 901 - 904. Retrieved 2007/10/03.