1,1,2-Triphenyl-1-propene

Base Information

• Chemical Name: 1,1,2-Triphenyl-1-propene
• CAS No.: 3677-70-1
• Molecular Formula: C21H18
• Molecular Weight: 270.374
• DSSTox Substance ID: DTXSID601337056
• Nikkaji Number: J709.006D
• Mol file: 3677-70-1.mol

Synonyms:methyl-triphenyl-ethylene;1,1,2-Triphenyl-1-propene;propene, 1,1,2-triphenyl-;DTXSID601337056;1,1',1''-Prop-1-ene-1,1,2-triyltribenzene;3677-70-1

Chemical Property of 1,1,2-Triphenyl-1-propene

Chemical Property:

• PSA: 0.00000
• LogP: 5.66560
• XLogP3: 6.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 270.140850574
• Heavy Atom Count: 21
• Complexity: 313

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C(C1=CC=CC=C1)C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of 1,1,2-Triphenyl-1-propene

There total 56 articles about 1,1,2-Triphenyl-1-propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1,1-diphenylprop-1-en-2-yl 4-methylbenzenesulfonate (849943-94-8) + phenylmagnesium chloride (100-59-4) → 1,1,2-triphenylprop-1-ene (3677-70-1)

Guidance literature:

phenylmagnesium chloride; With C₂₄H₅₂Cl₂O₁₂P₄Pd₂; In tetrahydrofuran; 1,4-dioxane; at 20 ℃; for 0.0833333h; Inert atmosphere;

1,1-diphenylprop-1-en-2-yl 4-methylbenzenesulfonate; In tetrahydrofuran; 1,4-dioxane; at 80 ℃; for 24h; Inert atmosphere;

DOI:10.1002/chem.201002386

Reference yield: 95.0%

1,1-diphenylprop-1-en-2-yl methanesulfonate (1323128-41-1) + phenylboronic acid (98-80-6) → 1,1,2-triphenylprop-1-ene (3677-70-1)

Guidance literature:

With potassium phosphate; 2-[2-(dicyclohexylphosphino)-phenyl]-1-methyl-1H-indole; palladium diacetate; triethylamine; In tert-butyl alcohol; at 50 ℃; for 4h; Inert atmosphere;

DOI:10.1039/c1cc12240a

Reference yield: 90.0%

1-Phenylprop-1-yne (673-32-5) + iodobenzene (591-50-4) + phenylboronic acid (98-80-6) → 1,1,2-triphenylprop-1-ene (3677-70-1)

Guidance literature:

With potassium hydrogencarbonate; bis(benzonitrile)palladium(II) dichloride; In water; N,N-dimethyl-formamide; at 100 ℃; for 12h;

DOI:10.1021/jo048265+

upstream raw materials:

2-chloro-propanoic acid, ethyl ester

di-tert-butyl peroxide

1,1,2-triphenyl-1-propanol

2,2,3-triphenyl-butyronitrile

Downstream raw materials:

1,1,2-Triphenylpropane

3-bromo-1,1,2-triphenyl-propene

2,3,3-triphenylacrylaldehyde

1,1,1-triphenylacetone

Refernces

• 1、 -. "Triphenylethylene multifunctional photoresponse compound as well as preparation method and application thereof". Paragraph 0066-0072. . Retrieved 2021/11/06.
• 2、 Du, Changle,Fu, Xingyang,Fu, Zhicheng,Luo, Yun,Xu, Jiaxi. "Microwave-assisted periselective annulation of triarylphosphenes with aldehydes and ketones". . p. 9526 - 9537. Retrieved 2020/12/15.