hexyl hydroperoxide

Base Information

• Chemical Name: hexyl hydroperoxide
• CAS No.: 4312-76-9
• Molecular Formula: C6H14O2
• Molecular Weight: 118.176
• Mol file: 4312-76-9.mol

Synonyms:

Chemical Property of hexyl hydroperoxide

Chemical Property:

• Vapor Pressure: 0.232mmHg at 25°C
• Boiling Point: 182.7°C at 760 mmHg
• Flash Point: 64.3°C
• Density: 0.899g/cm³

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hexyl hydroperoxide

There total 11 articles about hexyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

n-hexyl methanesulfonate (16156-50-6) → 1-hydroperoxy hexane (4312-76-9,9004-77-7)

Guidance literature:

With dihydrogen peroxide; potassium hydroxide; In methanol; water; at 20 ℃; for 20h;

DOI:10.1021/acs.joc.9b01979

Reference yield: 58.0%

1,1-bis(hexylperoxy)cyclododecane (1427511-73-6) → 1-hydroperoxy hexane (4312-76-9,9004-77-7) + cyclododecanone (830-13-7)

Guidance literature:

With sulfuric acid; water; In tetrahydrofuran; at 20 - 55 ℃; Reflux;

DOI:10.1021/jo4001564

Reference yield:

hexane (110-54-3) → n-hexan-3-ol (623-37-0) + n-hexan-2-ol (626-93-7) + 1-hydroperoxy hexane (4312-76-9,9004-77-7) + n-hexan-2-one (591-78-6) + n-hexan-3-one (589-38-8) + acetic acid (64-19-7,77671-22-8) + propionic acid (802294-64-0,79-09-4) + hexanal (66-25-1) + hexanoic acid (142-62-1) + butyric acid (107-92-6) + hexan-1-ol (111-27-3) + valeric acid (109-52-4)

Guidance literature:

With oxygen; In 1,2-dichloro-benzene; at 129.84 ℃; Product distribution / selectivity;

upstream raw materials:

n-hexyl methanesulfonate

1-Iodohexane

n-hexyldichloroborane

n-hexylmagnesium chloride

Downstream raw materials:

2-ethyltetrahydrofuran

hexane-1,4-diol

hexan-1-ol

hexanal

Refernces

• 1、 Groendyke, Brian J.,Modak, Atanu,Cook, Silas P.. "Fenton-Inspired C-H Functionalization: Peroxide-Directed C-H Thioetherification". . p. 13073 - 13091. Retrieved 2019/10/10.
• 2、 Zhan, Bi-Zeng,Moden, Bjoern,Dakka, Jihad,Santiesteban, Jose G.,Iglesia, Enrique. "Catalytic oxidation of n-hexane on Mn-exchanged zeolites: Turnover rates, regioselectivity, and spatial constraints". . p. 316 - 325. Retrieved 2008/03/13.