CID 15970856

Base Information

• Chemical Name: CID 15970856
• CAS No.: 37586-57-5
• Molecular Formula: C6H11BrMg
• Molecular Weight: 187.362
• DSSTox Substance ID: DTXSID80446785
• Mol file: 37586-57-5.mol

Synonyms:Magnesium, bromo(4-methyl-3-pentenyl)-;DTXSID80446785

Chemical Property of CID 15970856

Chemical Property:

• PSA: 0.00000
• LogP: -0.81920
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 185.98945
• Heavy Atom Count: 8
• Complexity: 47.1

Purity/Quality:

4-Methylpent-3-enylmagnesiumbromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CC[CH2-])C.[Mg+2].[Br-]

Technology Process of CID 15970856

There total 1 articles about CID 15970856 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-4-methylpent-3-ene (2270-59-9) → 4-methyl-3-pentenylmagnesium bromide (37586-57-5)

Guidance literature:

With magnesium; In diethyl ether;

DOI:10.1002/hlca.19800630627

Reference yield: 90.0%

4-methyloxetan-2-one (3068-88-0,32082-74-9,36536-46-6,65058-82-4) + 4-methyl-3-pentenylmagnesium bromide (37586-57-5) → racemic citronellic acid (502-47-6,57030-77-0)

Guidance literature:

With copper(l) iodide; In tetrahydrofuran; at -15 - -3 ℃; for 4h;

DOI:10.1016/0040-4039(80)80126-2

Reference yield: 90.0%

dimethoxy(diphenyl)silane (6843-66-9) + 4-methyl-3-pentenylmagnesium bromide (37586-57-5) → C19H24OSi (1100765-88-5)

Guidance literature:

In diethyl ether; at 0 ℃; for 1h; Inert atmosphere;

upstream raw materials:

1-bromo-4-methylpent-3-ene

Downstream raw materials:

γ-geraniol

4-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-benzoic acid methyl ester

ethyl (E)-3,7-dimethylocta-2,6-dienoate

Methyl-6-phenyl-1-heptene-5-ol-2

Refernces