2,3-Anthracenedicarbonitrile, 1,4-diphenyl-

Base Information

• Chemical Name: 2,3-Anthracenedicarbonitrile, 1,4-diphenyl-
• CAS No.: 376647-07-3
• Molecular Formula: C28H16N2
• Molecular Weight: 380.448
• Mol file: 376647-07-3.mol

Synonyms:

Chemical Property of 2,3-Anthracenedicarbonitrile, 1,4-diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3-Anthracenedicarbonitrile, 1,4-diphenyl-

There total 2 articles about 2,3-Anthracenedicarbonitrile, 1,4-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2,3-dicyano-1,4-diphenyl-1,4-oxide-2,3-dihydroanthracene → 2,3-dicyano-1,4-diphenylanthracene (376647-07-3)

Guidance literature:

With sulfuric acid; at 0 ℃; for 0.166667h;

DOI:10.1021/ja012382u

Reference yield:

1,3-diphenylnaphtho[2,3-c]furan (18929-57-2) → 2,3-dicyano-1,4-diphenylanthracene (376647-07-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / CH₂Cl₂

2: 94 percent / conc. H₂SO₄ / 0.17 h / 0 °C

With sulfuric acid; In dichloromethane;

DOI:10.1021/ja012382u

Reference yield: 3.9%

diphenylmaleonitrile (2450-56-8) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) + 2,3-dicyano-1,4-diphenylanthracene (376647-07-3) → [2(1),2(8),7(1),7(8)-tetraphenyldianthraco[b,g]-12,13,17,18-tetraphenyl-5,10,15,20-tetraazaporphyrinato(2-)]cobalt(II) (376647-06-2) + [2(1),2(8)-diphenylanthraco[b]-7,8,12,13,17,18-tetraphenyl-5,10,15,20-tetraazaporphyrinato(2-)]cobalt(II) (444989-59-7)

Guidance literature:

With lithium; In N,N-dimethyl-formamide; to soln. of 1-hexanol contg. Li added mixt. of diphenylmaleonitrile and 2,3-dicyano-1,4-diphenylanthracene; soln. stirred at 150°C for 1 h; most of solvent removed by passing N2 at this temp.; DMF and anhyd. CoCl2 added; stirred for 30 min.; soln. cooled; soln. poured into H2O; ppt. filtered; washed (H2O, MeOH); dried; sepd. and purified by chromy. (toluene as eluent); recrystd. (CH2Cl2/MeOH); elem. anal.;

DOI:10.1021/ja012382u

upstream raw materials:

1,3-diphenylnaphtho[2,3-c]furan

Downstream raw materials:

[2⁽¹⁾,2⁽⁸⁾,7⁽¹⁾,7⁽⁸⁾-tetraphenyldianthraco[b,g]-12,13,17,18-tetraphenyl-5,10,15,20-tetraazaporphyrinato^(2-)]cobalt(II)

[2⁽¹⁾,2⁽⁸⁾-diphenylanthraco[b]-7,8,12,13,17,18-tetraphenyl-5,10,15,20-tetraazaporphyrinato^(2-)]cobalt(II)

[2⁽¹⁾,2⁽⁸⁾-diphenylanthraco[b]-7,8,12,13,17,18-tetraphenyl-5,10,15,20-tetraazaporphyrinato^(2-)]nickel(II)

[2⁽¹⁾,2⁽⁸⁾,7⁽¹⁾,7⁽⁸⁾-tetraphenyldianthraco[b,g]-12,13,17,18-tetraphenyl-5,10,15,20-tetraazaporphyrinato^(2-)]nickel(II)

Refernces