N-(2,4-Dinitrophenyl)-L-tryptophan

Base Information

• Chemical Name: N-(2,4-Dinitrophenyl)-L-tryptophan
• CAS No.: 1655-51-2
• Molecular Formula: C17H14 N4 O6
• Molecular Weight: 370.321
• Hs Code.: 2933990090
• European Community (EC) Number: 216-738-3
• DSSTox Substance ID: DTXSID501297100
• Nikkaji Number: J195.289G
• Mol file: 1655-51-2.mol

Synonyms:DNP-L-tryptophan;1655-51-2;N-(2,4-Dinitrophenyl)-L-tryptophan;L-Tryptophan, N-(2,4-dinitrophenyl)-;(2S)-2-(2,4-dinitroanilino)-3-(1H-indol-3-yl)propanoic acid;EINECS 216-738-3;C17-H14-N4-O6;Tryptophan, N-(2,4-dinitrophenyl)-;SCHEMBL1229970;DTXSID501297100;(2S)-2-[(2,4-dinitrophenyl)amino]-3-(1H-indol-3-yl)propanoic acid;AKOS022181472;NSC 526958;(S)-2-(2,4-dinitrophenylamino)-3-(1H-indol-3-yl)propanoic acid;(S)-2-((2,4-Dinitrophenyl)amino)-3-(1H-indol-3-yl)propanoic acid

Chemical Property of N-(2,4-Dinitrophenyl)-L-tryptophan

Chemical Property:

• Vapor Pressure: 1.53E-20mmHg at 25°C
• Boiling Point: 699.6°Cat760mmHg
• Flash Point: 376.9°C
• PSA: 156.76000
• Density: 1.584g/cm³
• LogP: 4.21150
• Storage Temp.: −20°C
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 5
• Exact Mass: 370.09133418
• Heavy Atom Count: 27
• Complexity: 577

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(=CN2)CC(C(=O)O)NC3=C(C=C(C=C3)[N+](=O)[O-])[N+](=O)[O-]
• Isomeric SMILES: C1=CC=C2C(=C1)C(=CN2)C[C@@H](C(=O)O)NC3=C(C=C(C=C3)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of N-(2,4-Dinitrophenyl)-L-tryptophan

There total 2 articles about N-(2,4-Dinitrophenyl)-L-tryptophan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) + L-Tryptophan (73-22-3,27732-43-0,80206-30-0,27813-82-7) → N-(2,4-dinitrophenyl)-L-tryptophan (1655-51-2)

Guidance literature:

With ethanol; sodium hydrogencarbonate;

DOI:10.1021/ja01634a041

Reference yield:

N-(2,4-dinitrophenyl)-D,L-tryptophan (63628-23-9) → N-(2,4-dinitrophenyl)-D-tryptophan (63400-91-9) + N-(2,4-dinitrophenyl)-L-tryptophan (1655-51-2)

Guidance literature:

DOI:10.1021/ac950698c

upstream raw materials:

2,4-Dinitrofluorobenzene

L-Tryptophan

N-(2,4-dinitrophenyl)-D,L-tryptophan

Refernces