Benzenedodecanoic acid, methyl ester

Base Information

• Chemical Name: Benzenedodecanoic acid, methyl ester
• CAS No.: 38795-65-2
• Molecular Formula: C19H30O2
• Molecular Weight: 290.446
• Mol file: 38795-65-2.mol

Synonyms:

Chemical Property of Benzenedodecanoic acid, methyl ester

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenedodecanoic acid, methyl ester

There total 12 articles about Benzenedodecanoic acid, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(E)-12-Phenyl-dodec-11-enoic acid methyl ester → ω-phenyl dodecanoic acid methyl ester (38795-65-2)

Guidance literature:

With hydrogen; palladium on activated charcoal; In methanol; at 20 ℃; for 2h; atmospheric pressure;

DOI:10.1021/ac051141s

Reference yield: 95.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + 12-Phenyldodecanoic Acid (14507-27-8) → ω-phenyl dodecanoic acid methyl ester (38795-65-2)

Guidance literature:

In diethyl ether; at 0 ℃; for 12h;

DOI:10.1021/jm00369a027

Reference yield: 81.0%

(E)-methyl 12-phenyldodec-11-enoate → ω-phenyl dodecanoic acid methyl ester (38795-65-2)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In ethanol; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.bmc.2016.07.057

upstream raw materials:

diazomethane

12-Phenyldodecanoic Acid

methanol

11-bromoundecanoic acid

Downstream raw materials:

12-phenyl-1-dodecanol

12-Phenyldodecanoic Acid

12-phenyldodecyl iodide

ethyl 14-phenyltetradecanoate

Refernces

• 1、 Kovács, Ervin,Sághy, Péter,Turczel, Gábor,Tóth, Imre,Lendvay, Gy?rgy,Domján, Attila,Anastas, Paul T.,Tuba, Róbert. "Metathesis of renewable polyene feedstocks – Indirect evidences of the formation of catalytically active ruthenium allylidene species". supporting information. p. 213 - 217. Retrieved 2017/09/12.
• 2、 Ramon-Azcon, Javier,Galve, Roger,Sanchez-Baeza, Francisco,Marco, M.-Pilar. "Development of an enzyme-linked immunosorbent assay for the determination of the linear alkylbenzene sulfonates and long-chain sulfophenyl carboxylates using antibodies generated by pseudoheterologous immunization". . p. 71 - 81. Retrieved 2008/02/12.