apocamphor

Base Information

• Chemical Name: apocamphor
• CAS No.: 514-15-8
• Molecular Formula: C₉H₁₄O
• Molecular Weight: 138.21
• Mol file: 514-15-8.mol

Synonyms:α-fenchocamphorone;Norcamphor;7,7,dimethyl-bicyclo[2.2.1]heptan-2-one;camphor;7,7-dimethylnorboranone;7,7-dimethylbicyclo[2.2.1]heptan-2-one;

Chemical Property of apocamphor

Chemical Property:

• Melting Point: 107-110 °C
• Boiling Point: 196-197 °C
• PSA: 17.07000
• Density: 0.986±0.06 g/cm3(Predicted)
• LogP: 2.01160

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of apocamphor

There total 30 articles about apocamphor which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(-)-borneol (3588-22-5,26908-71-4,30884-63-0,32989-04-1,51153-09-4,51153-10-7,91605-15-1,111821-63-7,111821-64-8) → 7,7-dimethylbicyclo[2.2.1]heptan-2-one (514-15-8,32989-00-7,40550-41-2,110012-74-3)

Guidance literature:

With ruthenium trichloride; iodobenzene; potassium peroxymonosulfate; In water; acetonitrile; at 20 ℃; for 0.8h; Inert atmosphere;

DOI:10.1016/j.tet.2010.04.046

Reference yield: 99.0%

7,7-dimethylbicyclo<2.2.1>heptan-endo-2-ol (111821-63-7) → 7,7-dimethylnorbornanone (514-15-8,32989-00-7,40550-41-2,110012-74-3)

Guidance literature:

With ruthenium trichloride; iodobenzene; potassium peroxomonosulfate; In water; acetonitrile; at 20 ℃; for 0.8h;

DOI:10.1002/chem.200901953

Reference yield: 98.0%

7-spirocyclopropylnorbornanone (20454-77-7,32988-96-8,111197-62-7) → 7,7-dimethylnorbornanone (514-15-8,32989-00-7,40550-41-2,110012-74-3)

Guidance literature:

With hydrogen; platinum(IV) oxide; In acetic acid; for 16.5h; under 2585.7 Torr;

upstream raw materials:

fencholenic aldehyde

(+-)-camphenilone

7,7-dimethylnorboranone ketal

fenchene

Downstream raw materials:

2,7,7-trimethyl-exo-2-norbornanol

2,7,7-trimethyl-endo-2-norbornanol

7,7-dimethylbicyclo<2.2.1>heptane-2,3-dione

rac-2-methyl-1-phenylpropan-1-ol

Refernces

• 1、 Shibuya, Masatoshi,Nagasawa, Shota,Osada, Yuji,Iwabuchi, Yoshiharu. "Mechanistic insight into aerobic alcohol oxidation using NOx-nitroxide catalysis based on catalyst structure-activity relationships". . p. 10256 - 10268. Retrieved 2015/02/19.
• 2、 Yusubov, Mekhman S.,Nemykin, Victor N.,Zhdankin, Viktor V.. "Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species". experimental part. p. 5745 - 5752. Retrieved 2010/10/02.