2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoroheptyl methacrylate

Base Information

• Chemical Name: 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoroheptyl methacrylate
• CAS No.: 48076-44-4
• Molecular Formula: C11H7F13O2
• Molecular Weight: 418.155
• Hs Code.: 2916140000
• European Community (EC) Number: 256-351-7
• DSSTox Substance ID: DTXSID60197405
• Nikkaji Number: J877.250I
• Wikidata: Q81985553
• Mol file: 48076-44-4.mol

Synonyms:1H,1H-Perfluoroheptyl methacrylate;48076-44-4;2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoroheptyl methacrylate;2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptyl 2-methylprop-2-enoate;(Perfluorohexyl)methyl methacrylate;EINECS 256-351-7;SCHEMBL1536970;DTXSID60197405;OGTUUPXNYCOCKQ-UHFFFAOYSA-N;MFCD16621324;AKOS016015556;Methacrylic acid 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptyl ester

Chemical Property of 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoroheptyl methacrylate

Chemical Property:

• Vapor Pressure: 0.284mmHg at 25°C
• Boiling Point: 203°C at 760 mmHg
• Flash Point: 74.7°C
• PSA: 26.30000
• Density: 1.495g/cm³
• LogP: 4.84450
• XLogP3: 5.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 15
• Rotatable Bond Count: 8
• Exact Mass: 418.0238456
• Heavy Atom Count: 26
• Complexity: 561

Purity/Quality:

99% ^*data from raw suppliers

1H,1H-Perfluoroheptyl methacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoroheptyl methacrylate

There total 1 articles about 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoroheptyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptan-1-ol (375-82-6) + Methacryloyl chloride (920-46-7,26937-45-1) → 1H,1H-tridecafluoroheptyl methacrylate (48076-44-4)

Guidance literature:

With sulfonated coal; sulfuric acid; hydroquinone; In toluene; at 110 ℃; for 6h;

Reference yield:

1H,1H-tridecafluoroheptyl methacrylate (48076-44-4) → 2-(2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-heptyloxycarbonyl)-propane-1-sulfonatebenzyl-triethyl-ammonium; (93764-89-7)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium metabisulfite; hydroquinone; / aq. ethanol / 18 h / 78 °C

2: ethanol / 2 h / 78 °C

With sodium disulfite; hydroquinone; In ethanol;

upstream raw materials:

2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptan-1-ol

Methacryloyl chloride

Downstream raw materials:

2-(2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-heptyloxycarbonyl)-propane-1-sulfonatebenzyl-triethyl-ammonium;

Refernces