2-(Bromomethyl)-3-methylnaphthalene

Base Information

• Chemical Name: 2-(Bromomethyl)-3-methylnaphthalene
• CAS No.: 39171-57-8
• Molecular Formula: C12H11Br
• Molecular Weight: 235.12000
• European Community (EC) Number: 688-843-6
• Nikkaji Number: J445.807I
• Mol file: 39171-57-8.mol

Synonyms:2-(bromomethyl)-3-methylnaphthalene;2-Bromomethyl-3-methylnaphthalene;39171-57-8;2-bromomethyl-3-methyl-naphthalene;starbld0048127;SCHEMBL1520850;2-bromomethyl3-methylnaphthalene;WNKGWGYRZPIHSQ-UHFFFAOYSA-N;AKOS004907977;AT24776

Chemical Property of 2-(Bromomethyl)-3-methylnaphthalene

Chemical Property:

• PSA: 0.00000
• LogP: 4.04310
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 234.00441
• Heavy Atom Count: 13
• Complexity: 167

Purity/Quality:

99% ^*data from raw suppliers

2-BROMOMETHYL-3-METHYL-NAPHTHALENE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC2=CC=CC=C2C=C1CBr

Technology Process of 2-(Bromomethyl)-3-methylnaphthalene

There total 4 articles about 2-(Bromomethyl)-3-methylnaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

2-hydroxymethyl-3-methylnaphthalene (31554-16-2) → 2-Bromomethyl-3-methylnaphthalene (39171-57-8)

Guidance literature:

With phosphorus tribromide; In diethyl ether;

Reference yield: 50.0%

2,3-dimethylnaphthalene (581-40-8) → 2-Bromomethyl-3-methylnaphthalene (39171-57-8)

Guidance literature:

With N-Bromosuccinimide;

DOI:10.1021/ja00373a036

Reference yield:

2,3-dimethylnaphthalene (581-40-8) → 2,3-di(bromomethyl)naphthalene (38998-33-3) + 2-Bromomethyl-3-methylnaphthalene (39171-57-8)

Guidance literature:

With N-Bromosuccinimide; In tetrachloromethane; Heating;

DOI:10.1021/ja00229a008

upstream raw materials:

2,3-dimethylnaphthalene

formaldehyd

2-hydroxymethyl-3-methylnaphthalene

Downstream raw materials:

4,10-Dimethylphenanthren

trans-12b,12c-dimethyl-12b,12c-dihydrobenzopyrene

trans-1-<2-(3-methylnaphthyl)>-2-phenylethene

2-Benzenesulfonylmethyl-3-methyl-naphthalene

Refernces

• 1、 Saltiel, Jack,Choi, Jong-Oh,Sears, Donald F. Jr.,Eaker, David W.,Mallory, Frank B.,Mallory, Clelia W.. "Effect of Spectral Shifts on the Resolution of trans-1-(2-Naphthyl)-2-phenylethene Conformer UV Spectra Based on Principal Component Analysis with Self-Modeling". . p. 13162 - 13170. Retrieved 2007/10/02.
• 2、 -. "Novel naphthalenyl-3H-1,2,3,5-oxathiadiazole 2-oxides useful as antihyperglycemic agents". . . Retrieved 2008/06/13.