CYCLOPENTADIENYLMOLYBDENUM TRICARBONYL DIMER

Base Information

• Chemical Name: CYCLOPENTADIENYLMOLYBDENUM TRICARBONYL DIMER
• CAS No.: 12091-64-4
• Molecular Formula: C16H10 Mo2 O6
• Molecular Weight: 490.132
• Hs Code.: 29319090
• Mol file: 12091-64-4.mol

Synonyms:Molybdenum,hexacarbonyldi-p-cyclopentadienyldi-(8CI); Molybdenum, hexacarbonyldicyclopentadienyldi- (7CI); Bis(p-cyclopentadienylmolybdenumtricarbonyl); Bis[(h5-cyclopentadienyl)tricarbonylmolybdenum]; Bis[tricarbonyl(h5-cyclopentadienyl)molybdenum];Cyclopentadienyltricarbonylmolybdenum dimer;Hexacarbonylbis(cyclopentadienyl)dimolybdenum; Hexacarbonylbis(h5-cyclopentadienyl)dimolybdenum;Hexacarbonylbis(h5-cyclopentadienyl)dimolybdenum(I);Hexacarbonylbis(h5-cyclopentadienyl)dimolybdenum(Mo-Mo);Hexacarbonyldi-p-cyclopentadienyldimolybdenum

Chemical Property of CYCLOPENTADIENYLMOLYBDENUM TRICARBONYL DIMER

Chemical Property:

• Appearance/Colour: dark red crystalline solid
• Melting Point: 222 °C (dec.)(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.79500
• Sensitive.: Air Sensitive
• Water Solubility.: It is insoluble in water.

Purity/Quality:

98%Min ^*data from raw suppliers

Cyclopentadienylmolybdenum tricarbonyl dimer, min. 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: It is widely used as a chemical intermediate in the laboratories, manufacture purposes, chemical and pharmaceutical intemediate.

Technology Process of CYCLOPENTADIENYLMOLYBDENUM TRICARBONYL DIMER

There total 3 articles about CYCLOPENTADIENYLMOLYBDENUM TRICARBONYL DIMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

Na[CpMo(CO)3] (12107-35-6) → ((C5H5)Mo(CO)3)2 (12091-64-4) + (η5-cyclopentadienyl)MoCl(CO)3 + (C5H5)Mo2(CO)6(C5H4C4H7O) (113753-77-8)

Guidance literature:

With tetrahydrofuran; thionyl chloride; In tetrahydrofuran; THF soln. of SOCl2 was added dropwise (15 min) to a stirred soln. of CpMo(CO)3Na in THF at -97°C under nitrogen atmosphere; evapd., residue was extd. with Et2O, chromd. on a SiO2 column (eluent Et2O-light petroleum, then Et2O); (CpMo(CO)3)2 was identified by IR and (1)H NMR spectra, elem. anal. for CpMoCl(CO)3 and THF-substituted dimer (crystd. from Et2O-petroleum ether);

Reference yield: 35.0%

CpMo(CO)3H (12176-06-6) → ((C5H5)Mo(CO)3)2 (12091-64-4) + (η5-cyclopentadienyl)MoCl(CO)3

Guidance literature:

With thionyl chloride; In tetrahydrofuran; THF soln. of SOCl2 was slowly added to a stirred soln. of Mo-complex inTHF at room temp. under N2 atmosphere; solvent was removed under vac., residue extd. with Et2O, sepd. by a column chromy. (eluent petroleum ether followed by Et2O-petroleum ether);

Reference yield: 32.0%

Na[CpMo(CO)3] (12107-35-6) → ((C5H5)Mo(CO)3)2 (12091-64-4) + (η5-cyclopentadienyl)MoCl(CO)3

Guidance literature:

With thionyl chloride; In tetrahydrofuran; THF soln. of SOCl2 was added dropwise to a stirred soln. of CpMo(CO)3Nain THF at room temp. under nitrogen atmosphere;

upstream raw materials:

CpMo(CO)₃H

Na[CpMo(CO)3]