N-Phenyl-9-aminophenanthrene

Base Information

• Chemical Name: N-Phenyl-9-aminophenanthrene
• CAS No.: 3920-79-4
• Molecular Formula: C20H15N
• Molecular Weight: 269.346
• European Community (EC) Number: 695-662-6
• Nikkaji Number: J1.099.865D
• ChEMBL ID: CHEMBL3601314
• Mol file: 3920-79-4.mol

Synonyms:N-phenyl-9-phenanthreneamine;N-Phenyl-9-phenanthrenamine;9-(phenylamino)phenanthrene;[9]Phenanthryl-phenyl-amin;9-Anilino-phenanthren;[9]phenanthryl-phenyl-amine;9-anilinophenanthracene;

Chemical Property of N-Phenyl-9-aminophenanthrene

Chemical Property:

• Melting Point: 133-137°C
• PSA: 12.03000
• LogP: 5.80960
• XLogP3: 6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 269.120449483
• Heavy Atom Count: 21
• Complexity: 333

Purity/Quality:

98.5% ^*data from raw suppliers

N-Phenyl-9-phenanthrenamine 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)NC2=CC3=CC=CC=C3C4=CC=CC=C42

Technology Process of N-Phenyl-9-aminophenanthrene

There total 11 articles about N-Phenyl-9-aminophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.1%

→ N-phenyl-N-(9-phenanthryl)amine (3920-79-4)

Guidance literature:

With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In cyclohexane; toluene; for 2h; Inert atmosphere; Reflux;

Reference yield: 86.0%

9-bromophenanthrene (573-17-1) + aniline (62-53-3) → N-phenyl-N-(9-phenanthryl)amine (3920-79-4)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; potassium tert-butylate; In toluene; at 85 ℃; for 4h;

Reference yield: 85.0%

1'-phenylspiro (79918-17-5) → N-phenyl-N-(9-phenanthryl)amine (3920-79-4)

Guidance literature:

With hydrogenchloride; In acetone; for 0.333333h; Ambient temperature;

DOI:10.1021/jo00341a019

upstream raw materials:

9-chlorophenanthrene

sodium anilide

aniline

4-nitrophenyl azide

Downstream raw materials:

benzo[c]isoindolo[2,1,7-mna]phenothiazin-14-one

C₄₂H₂₅N

C₂₈H₂₁N

Refernces

• 1、 -. "Organic compound, and electronic element and electronic device using same". Paragraph 0150-0152; 0155. . Retrieved 2021/07/14.
• 2、 Wu, Ke,Rong, Qiang,Sun, Nan,Hu, Baoxiang,Shen, Zhenlu,Jin, Liqun,Hu, Xinquan. "Nickel-Catalyzed Amination of Aryl Nitriles for Accessing Diarylamines through C?CN Bond Activation". . p. 4708 - 4713. Retrieved 2021/08/27.