1-Methylquinolinium iodide

Base Information

• Chemical Name: 1-Methylquinolinium iodide
• CAS No.: 3947-76-0
• Molecular Formula: C10H10N.I
• Molecular Weight: 271.101
• Hs Code.: 2933499090
• NSC Number: 72308
• UNII: 3743X5VE2U
• DSSTox Substance ID: DTXSID40960098
• Wikipedia: Quinoline methiodide,Quinoline_methiodide
• Wikidata: Q82941144
• Mol file: 3947-76-0.mol

Synonyms:1-methylquinolinium;1-methylquinolinium bromide;1-methylquinolinium chloride;1-methylquinolinium hydroxide;1-methylquinolinium iodide;1-methylquinolinium mesylate;1-methylquinolinium monopicrate;1-methylquinolinium pentaiodide;1-methylquinolinium perchlorate;1-methylquinolinium tetrafluoroborate (1-);1-methylquinolinium triiodide

Chemical Property of 1-Methylquinolinium iodide

Chemical Property:

• PSA: 3.88000
• LogP: -1.33170
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 270.98580
• Heavy Atom Count: 12
• Complexity: 133

Purity/Quality:

99%min ^*data from raw suppliers

1-METHYLQUINOLINIUM IODIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+]1=CC=CC2=CC=CC=C21.[I-]
• Uses: Quinoline Methyl Idodide is a reagent used in the preparation of chiral boron(III)chelates.

Technology Process of 1-Methylquinolinium iodide

There total 4 articles about 1-Methylquinolinium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

quinoline (91-22-5) + methyl iodide (74-88-4) → N-methylquinolinium iodide (3947-76-0)

Guidance literature:

In acetonitrile;

DOI:10.1039/c9ob02466b

Reference yield: 93.0%

→ N-methylquinolinium iodide (3947-76-0)

Guidance literature:

Reference yield: 80.0%

N-methylacridinium iodide (948-43-6) + 2-(indol-3-yl)-1-methyl-1,2-dihydroquinoline (90731-53-6) → N-methylquinolinium iodide (3947-76-0) + 9-(1H-indol-3-yl)-10-methylacridinium iodide (75960-64-4)

Guidance literature:

In acetonitrile; for 3h;

DOI:10.1007/BF00506395

upstream raw materials:

quinoline

methyl iodide

N-methylacridinium iodide

2-(indol-3-yl)-1-methyl-1,2-dihydroquinoline

Downstream raw materials:

2-(1-methyl-1,4-dihydro-quinolin-4-yl)-2-phenyl-propionitrile

quinoline

1-methyl-3-(o-nitrophenyl)-1H-quinoline-2-one

3-iodo-1-methylquinolin-2(1H)-one

Refernces

• 1、 Murthy, A. S. N.,Bhardwaj, A. P.. "Charge-transfer interactions with N-methylquinolinium ion as electron acceptor". . p. 415 - 418. Retrieved 1983.
• 2、 Martinez-Haya,Luna,Hijarro,Martinez-Valero,Miranda,Marin. "Photocatalytic degradation of phenolic pollutants using N-methylquinolinium and 9-mesityl-10-methylacridinium salts". . p. 243 - 251. Retrieved 2019.
• 3、 Algoazy, Nawaf,Knight, Julian G.,Waddell, Paul G.,Aerts, Roy,Herrebout, Wouter,Al-Sharif, Hatun H. T.,Karlsson, Joshua K. G.,Harriman, Anthony. "Synthesis, Structure and Photophysical Properties of a New Class of Inherently Chiral Boron(III) Chelates—The tert-Leucine Complexes". . p. 5246 - 5258. Retrieved 2021.
• 4、 Benson, Christopher R.,Cox, Natalie M.,Erbas-Cakmak, Sundus,Flood, Amar H.,Gao, Xinfeng,Liu, Yun,Pink, Maren,Qiao, Bo,Raghavachari, Krishnan,Sadhukhan, Tumpa,VanDenburgh, Katherine L.. "Multi-state amine sensing by electron transfers in a BODIPY probe". . p. 431 - 440. Retrieved 2020.
• 5、 Yan, Xu,Liu, Chun-Fang,An, Xian-Tao,Ge, Xiao-Min,Zhang, Qing,Pang, Lin-Han,Bao, Xu,Fan, Chun-An. "Copper-Catalyzed (4+1) Cascade Annulation of Terminal Alkynes with 2-(Tosylmethyl)anilines: Synthesis of 2,3-Disubstituted Indoles". supporting information. p. 8905 - 8909. Retrieved 2021/11/24.