DIMETHYL CYCLOPENTANE-1,3-DICARBOXYLATE

Base Information

• Chemical Name: DIMETHYL CYCLOPENTANE-1,3-DICARBOXYLATE
• CAS No.: 39590-04-0
• Molecular Formula: C₉H₁₄O₄
• Molecular Weight: 186.208
• Hs Code.: 2918300090
• Mol file: 39590-04-0.mol

Synonyms:Cis-dimethyl cyclopentane-1,3-dicarboxylate;cis-1,3-Dimethoxycarbonylcyclopentane;dimethyl (1S,3R)-cyclopentane-1,3-dicarboxylate;dimethyl cis-cyclopentane-1,3-dicarboxylate;dimethyl cis-1,3-cyclopentanedicarboxylate;cis-1,3-dicarbomethoxycyclopentane;cis-1,3-Cyclopentandicarbonsaeure-dimethylester;1,3-Cyclopentanedicarboxylic acid,dimethyl ester,cis;cis-Bis(carbomethoxy)cyclopentane;

Chemical Property of DIMETHYL CYCLOPENTANE-1,3-DICARBOXYLATE

Chemical Property:

• PSA: 52.60000
• LogP: 0.74870

Purity/Quality:

99% ^*data from raw suppliers

Dimethyl(1R,3S)-Cyclopentane-1,3-dicarboxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIMETHYL CYCLOPENTANE-1,3-DICARBOXYLATE

There total 7 articles about DIMETHYL CYCLOPENTANE-1,3-DICARBOXYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

methanol (67-56-1) + carbon monoxide (201230-82-2) + cyclopentene (142-29-0) → methyl cyclopentane carboxylate (4630-80-2) + methyl cyclopent-2-ene-1-carboxylate (2258-56-2) + (1R,3S)-dimethyl cyclopentane-1,3-dicarboxylate (39590-04-0,190137-08-7) + methyl cyclopent-3-ene-1-carboxylate (58101-60-3)

Guidance literature:

With methanesulfonic acid; oxygen; palladium diacetate; NPMoV; at 50 ℃; for 4h; under 760 Torr;

DOI:10.1021/jo0255779

Reference yield:

methanol (67-56-1) + norborn-2-ene (498-66-8) → methylene chloride (74-87-3) + (1R,3S)-dimethyl cyclopentane-1,3-dicarboxylate (39590-04-0,190137-08-7) + 1,3-Cyclopentandicarbaldehyd-bis(dimethylacetal) (58157-26-9) + 3-(Dimethoxymethyl)-1-cyclopentancarbonsaeure-methylester (83126-23-2)

Guidance literature:

With hydrogenchloride; ozone; Product distribution; -78 deg to r.t.;

Reference yield:

methanol (67-56-1) → dimethyl cyclopentan-1,3-dicarboxylate (2435-36-1,39590-04-0,62959-14-2,111138-57-9)

Guidance literature:

With hydrogenchloride;

upstream raw materials:

methanol

norborn-2-ene

carbon monoxide

cyclopentene

Downstream raw materials:

(1R,3S)-3-Isocyanato-cyclopentanecarboxylic acid

(1S,3R)-3-Carbamoyl-cyclopentanecarboxylic acid

(1S,3R)-3-aminocyclopentanecarboxylic acid

(1R,3S)-3-aminocyclopentanecarboxylic acid

Refernces

• 1、 Morimoto,Terao,Achiwa. "Enzymes and catalysts. I. Pig liver esterase-catalyzed hydrolysis of heterocyclic diesters.". . p. 2266 - 2271. Retrieved 2007/10/02.