Propylphosphine

Base Information

• Chemical Name: Propylphosphine
• CAS No.: 40200-59-7
• Molecular Formula: C3H9P
• Molecular Weight: 76.0782
• DSSTox Substance ID: DTXSID80562575
• Metabolomics Workbench ID: 55232
• Nikkaji Number: J607.954G
• Wikidata: Q27116605
• Mol file: 40200-59-7.mol

Synonyms:propylphosphine;propylphosphane;n-propylphosphine;PrPH2;40200-59-7;mono-n-propylphosphine;CHEBI:35891;DTXSID80562575;NNOBHPBYUHDMQF-UHFFFAOYSA-N;Q27116605

Chemical Property of Propylphosphine

Chemical Property:

• PSA: 13.59000
• LogP: 1.27150
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 76.044187285
• Heavy Atom Count: 4
• Complexity: 7.2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCP

Technology Process of Propylphosphine

There total 7 articles about Propylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

propyl bromide (106-94-5) → 4-[2,3-di(tert-butoxycarbonyl)guanidino]-4’-[4-(tert-butoxycarbonyl)aminobutanamido]diphenylethylene (40200-59-7)

Guidance literature:

With dihydrogen phosphide sodium; In various solvent(s); at 30 ℃; for 2h;

DOI:10.1080/10426500008045218

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → tris-n-propylphosphine (2234-97-1) + 4-[2,3-di(tert-butoxycarbonyl)guanidino]-4’-[4-(tert-butoxycarbonyl)aminobutanamido]diphenylethylene (40200-59-7)

Guidance literature:

With phosphorous; methyl iodide;

Reference yield:

diethyl propylphosphonite (51825-26-4) → 4-[2,3-di(tert-butoxycarbonyl)guanidino]-4’-[4-(tert-butoxycarbonyl)aminobutanamido]diphenylethylene (40200-59-7)

Guidance literature:

With lithium aluminium tetrahydride; In toluene; at 0 ℃; for 16h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic301504p

upstream raw materials:

propene

propyl bromide

1-hydroxypropyldiphenylphosphonate

1-iodo-propane

Refernces

• 1、 Davies, Robert P.,Patel, Laura,White, Andrew J. P.. "Preparations of metal trichalcogenophosphonates from organophosphonate esters". . p. 11594 - 11601,8. Retrieved 2020/10/15.
• 2、 Cabioch, Jean-Luc,Pellerin, Bruno,Denis, Jean-Marc. "SYNTHESIS OF PRIMARY α-CHLOROPHOSPHINES BY A CHEMOSELECTIVE REDUCTION OF α-CHLOROPHOPHONATES". . p. 27 - 32. Retrieved 2007/10/02.