Benzenetellurol, sodium salt

Base Information

• Chemical Name: Benzenetellurol, sodium salt
• CAS No.: 41422-67-7
• Molecular Formula: C6H6Te.Na
• Molecular Weight: 227.695
• Mol file: 41422-67-7.mol

Synonyms:

Chemical Property of Benzenetellurol, sodium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenetellurol, sodium salt

There total 4 articles about Benzenetellurol, sodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenyl ditelluride (32294-60-3) → sodium phenyltelluride (41422-67-7)

Guidance literature:

With sodium; In tetrahydrofuran; for 18h; Heating;

DOI:10.1016/S0040-4039(00)61909-3

Reference yield:

phenyllithium (591-51-5) → sodium phenyltelluride (41422-67-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: tellurium / tetrahydrofuran; cyclohexane; diethyl ether / 1 h / 21 °C / Inert atmosphere

1.2: 0 °C / Inert atmosphere

2.1: tetrahydrofuran; cyclohexane; diethyl ether / -78 °C / Inert atmosphere

3.1: sodium tetrahydroborate / ethanol / Inert atmosphere

With tellurium; sodium tetrahydroborate; In tetrahydrofuran; diethyl ether; ethanol; cyclohexane;

DOI:10.1002/zaac.201800302

Reference yield:

benzenetellurolate lithium salt (52251-60-2) → sodium phenyltelluride (41422-67-7)

Guidance literature:

Multi-step reaction with 2 steps

1: tin(IV) chloride / tetrahydrofuran; cyclohexane; diethyl ether / Inert atmosphere

2: sodium tetrahydroborate / ethanol / Inert atmosphere

With sodium tetrahydroborate; tin(IV) chloride; In tetrahydrofuran; diethyl ether; ethanol; cyclohexane;

DOI:10.1002/zaac.201800302

upstream raw materials:

diphenyl ditelluride

phenyllithium

benzenetellurolate lithium salt

phenyltellurotrimethylsilane

Downstream raw materials:

1,1,1,2,2,3,3,4,4-nonafluoro-6-iodo-5-decene

1-(benzylseleno)-5-hexyl (phenyltelluro)formate

cyclohexyl (phenyltelluro)formate

methylphenyltelluride

Refernces

• 1、 Masuda, Kengo,Nagatomo, Masanori,Inoue, Masayuki. "Direct assembly of multiply oxygenated carbon chains by decarbonylative radical-radical coupling reactions". . p. 207 - 212. Retrieved 2017.
• 2、 Beckmann, Jens,Heinrich, Darina,Mebs, Stefan. "Molecular structure and real-space bonding descriptors (AIM, ELI-D) of Phenyl(triphenylstannyl)telluride". . p. 2129 - 2133. Retrieved 2013.
• 3、 Behr, Sandra,Bestvater, Thorsten,Feldmann, Arnold,Kirschbaum, Kristin,Conrad, Olaf,Giolando, Dean M.. "Syntheses and Structures of Zinc(tmeda)bis(aryltellurolato) and its Facile Chalcogenospecific Ligand Exchange Reactivity". . p. 1431 - 1438. Retrieved 2018/09/25.