Benzene, (4-methylpentyl)-

Base Information

• Chemical Name: Benzene, (4-methylpentyl)-
• CAS No.: 4215-86-5
• Molecular Formula: C12H18
• Molecular Weight: 162.275
• Hs Code.: 2902909090
• Mol file: 4215-86-5.mol

Synonyms:Benzene, (4-methylpentyl)-;4-methyl-1-phenylpentane;2-methyl-5-phenylpentane;i-hexylbenzene;1-Phenyl-4-methylpentane;isohexylbenzene;

Chemical Property of Benzene, (4-methylpentyl)-

Chemical Property:

• Melting Point: -25.43°C (estimate)
• Refractive Index: 1.4969 (estimate)
• Boiling Point: 217°C
• PSA: 0.00000
• Density: 0.8568
• LogP: 3.66530

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzene, (4-methylpentyl)-

There total 38 articles about Benzene, (4-methylpentyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[(1Z)-4-methyl-1-penten-1-yl]benzene (54624-34-9) → isohexylbenzene (4215-86-5)

Guidance literature:

With palladium on activated charcoal; hydrogen; In ethyl acetate; for 3h; Inert atmosphere;

DOI:10.1021/ja5015508

Reference yield: 90.0%

2-(2-iodophenyl)ethyl methyl 4-methyl-1-phenylpentan-3-yl phosphite (794521-43-0) → isohexylbenzene (4215-86-5) + 1-(2-methyl-1-phenethyl-propoxy)-3,4-dihydro-benzo[c][1,2]oxaphosphinine 1-oxide

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 2h; Heating;

DOI:10.1021/ja0462777

Reference yield: 90.0%

1-Bromo-3-phenylpropane (637-59-2) + isopropylmagnesium chloride (1068-55-9) → isohexylbenzene (4215-86-5)

Guidance literature:

With C₁₇H₂₁CuN₄O⁽¹⁺⁾*CF₃O₃S^(1-); lithium methanolate; In tetrahydrofuran; at 0 ℃; for 8h; Schlenk technique; Inert atmosphere;

DOI:10.1039/C8DT03210F

upstream raw materials:

4-methyl-1-phenylpentan-1-one

benzyl bromide

i-pentyl bromide

ethylbenzene

Downstream raw materials:

2,2,3,3,3-pentafluoropropyl (4-methyl-1-phenylpentyl)sulfamate

Refernces

• 1、 Pandiri, Hanumanprasad,Gonnade, Rajesh G.,Punji, Benudhar. "Synthesis of quinolinyl-based pincer copper(ii) complexes: an efficient catalyst system for Kumada coupling of alkyl chlorides and bromides with alkyl Grignard reagents". supporting information. p. 16747 - 16754. Retrieved 2018/12/05.
• 2、 Bess, Elizabeth N.,Deluca, Ryan J.,Tindall, Daniel J.,Oderinde, Martins S.,Roizen, Jennifer L.,Du Bois,Sigman, Matthew S.. "Analyzing site selectivity in Rh2(esp)2-catalyzed intermolecular C-H amination reactions". supporting information. p. 5783 - 5789. Retrieved 2014/05/06.