TRICYCLOHEXYLPHOSPHINE SULFIDE

Base Information

• Chemical Name: TRICYCLOHEXYLPHOSPHINE SULFIDE
• CAS No.: 42201-98-9
• Molecular Formula: C18H33PS
• Molecular Weight: 312.5
• Mol file: 42201-98-9.mol

Synonyms:Tricyclohexylphosphine sulfide;Phosphine sulfide,tricyclohexyl;Tricyclohexyl-phosphinsulfid;tricyclohexylphosphine sulphide;thiotricyclohexylphosphine;

Chemical Property of TRICYCLOHEXYLPHOSPHINE SULFIDE

Chemical Property:

• PSA: 41.90000
• LogP: 7.11460

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of TRICYCLOHEXYLPHOSPHINE SULFIDE

There total 14 articles about TRICYCLOHEXYLPHOSPHINE SULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohexylmagnesium bromide (931-50-0) → tricyclohexylphosphine sulfide (42201-98-9)

Guidance literature:

Multi-step reaction with 2 steps

1: PCl₃

2: sulfur

With sulfur; phosphorus trichloride;

DOI:10.1002/zaac.19542770505

Reference yield:

tricyclohexylphosphine (2622-14-2) → tricyclohexylphosphine sulfide (42201-98-9)

Guidance literature:

With sulfur;

DOI:10.1021/jo01054a064 DOI:10.1002/zaac.19542770505

Reference yield:

phosphorus sulphochloride + cyclohexyl chloride (542-18-7) → tricyclohexylphosphine sulfide (42201-98-9)

Guidance literature:

With magnesium; In Isopropylbenzene;

upstream raw materials:

cyclohexylmagnesiumchloride

tricyclohexylphosphine

1H-imidazole-1-carbothioic acid O-cyclohexyl ester

cyclohexanol

Downstream raw materials:

(C₆H₁₁)3PS*SO₃

CoI₂(SPCy₃)2

tricyclohexylphosphine

CoCl₂(SPCy₃)2

Refernces

• 1、 Sato, Akinori,Yorimitsu, Hideki,Oshima, Koichiro. "Radical phosphination of organic halides and alkyl imidazole-1- carbothioates". . p. 4240 - 4241. Retrieved 2007/10/03.
• 2、 Cross, Wendy I.,Godfrey, Stephen M.,Jackson, Sheena L.,McAuliffe, Charles A.,Pritchard, Robin G.. "The reaction of the tertiary phosphine sulfides R3PS (R = Ph, Me2N or C6H11) with X2 (X2 = I2, Br2, IBr or ICl); structural characterisation of the CT complexes (Me . p. 2225 - 2230. Retrieved 2007/10/03.