Benzoyl azide, 3,5-dinitro-

Base Information

• Chemical Name: Benzoyl azide, 3,5-dinitro-
• CAS No.: 42444-51-9
• Molecular Formula: C7H3N5O5
• Molecular Weight: 237.131
• Mol file: 42444-51-9.mol

Synonyms:

Chemical Property of Benzoyl azide, 3,5-dinitro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoyl azide, 3,5-dinitro-

There total 7 articles about Benzoyl azide, 3,5-dinitro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3,5-dinitrobenzoic acid potassium salt (16345-42-9) → 3,5-dinitrobenzoyl azide (42444-51-9)

Guidance literature:

With sodium azide; tetrabutylammomium bromide; O-phenyl phosphorodichloridate; In dichloromethane; for 1.5h; Ambient temperature;

Reference yield: 99.0%

3,5-dinitrobenoyl chloride (99-33-2) → 3,5-dinitrobenzoyl azide (42444-51-9)

Guidance literature:

With polymer-supported azide ion reagent; In chloroform; for 2h; Ambient temperature;

Reference yield: 84.0%

3,5-dinitrobenzoic acid (99-34-3) → 3,5-dinitrobenzoyl azide (42444-51-9)

Guidance literature:

With pyridine; sodium azide; tetrabutylammomium bromide; <(chlorosulfinyloxy)methylene>dimethylammonium chloride; In dichloromethane; for 20h; Ambient temperature;

DOI:10.1016/S0040-4039(01)81386-1

upstream raw materials:

3,5-dinitrobenzohydrazide

3,5-dinitrobenoyl chloride

3,5-dinitrobenzoic acid

3,5-dinitrobenzoic acid potassium salt

Downstream raw materials:

(2RS,4'R,8'R)-O-(3,5-dinitro-phenylcarbamoyl)-α-tocopherol

3,5-dinitrobenzamide

(E)-N-[{2-(methoxyimino)cyclohexyl}methyl]-3,5-dinitrobenzamide

(3,5-Dinitro-phenyl)-carbamic acid (1R,2S)-1-cyclohexyl-2-methyl-but-3-enyl ester

Refernces

• 1、 Güng?r, Tu?ba,Tokay, Esra,Güven Gülhan, ünzile,Hac?o?lu, Nelin,?elik, Ayhan,K??kar, Feray,Ay, Mehmet. "Prodrugs for nitroreductase based cancer therapy-4: Towards prostate cancer targeting: Synthesis of N-heterocyclic nitro prodrugs, Ssap-NtrB enzymatic activation and anticancer evaluation". . . Retrieved 2020/11/16.
• 2、 Basavaprabhu,Narendra,Lamani, Ravi S.,Sureshbabu, Vommina V.. "T3P (propylphosphonic anhydride) mediated conversion of carboxylic acids into acid azides and one-pot synthesis of ureidopeptides". experimental part. p. 3002 - 3005. Retrieved 2010/07/10.