(9Z,12E)-9,12-Tetradecadien-1-ol

Base Information

• Chemical Name: (9Z,12E)-9,12-Tetradecadien-1-ol
• CAS No.: 42521-46-0
• Molecular Formula: C14H26O
• Molecular Weight: 210.36
• Mol file: 42521-46-0.mol

Synonyms:(9Z,12E)-TETRADECADIENOL;(9Z,12E)-9,12-Tetradecadien-1-ol;(Z,E)-9,12-tetradecadiene-1-ol;(Z,E)-9,12-tetradecadienol;(Z,E)-tetradeca-9,12-dien-1-ol;(9Z,12E)-Tetradec-9,12-dien-1-ol;(9Z,12E)-tetradeca-9,12-dien-1-ol;

Chemical Property of (9Z,12E)-9,12-Tetradecadien-1-ol

Chemical Property:

• Boiling Point: 98-99 °C(Press: 0.1 Torr)
• PKA: 15.20±0.10(Predicted)
• PSA: 20.23000
• Density: 0.860±0.06 g/cm3(Predicted)
• LogP: 4.23180

Purity/Quality:

99%,98%, ^*data from raw suppliers

(9Z,12E)-Tetradecadien-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: (9Z,12E)-Tetradecadien-1-ol can be used in biological study of sequence, identification, and functional characterization of sex pheromone receptors in beet armyworms.

Technology Process of (9Z,12E)-9,12-Tetradecadien-1-ol

There total 34 articles about (9Z,12E)-9,12-Tetradecadien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1-<(tetrahydro-2H-pyran-2-yl)oxy> 9Z, 12E-tetradecadiene (112464-06-9) → Tetradeca-cis-9,trans-12-dien-1-ol (42521-46-0,51937-00-9)

Guidance literature:

With toluene-4-sulfonic acid; In methanol; for 2h; Heating;

DOI:10.1007/BF00598272

Reference yield: 85.0%

(E)-Tetradec-12-en-9-yn-1-ol (42521-44-8) → Tetradeca-cis-9,trans-12-dien-1-ol (42521-46-0,51937-00-9)

Guidance literature:

With hydrogen; P-2 Ni; In ethanol; at 25 ℃;

DOI:10.1007/bf02757427

Reference yield: 71.0%

Tetradec-9Z,12E-dien-1-yl Acetate (30507-70-1) → Tetradeca-cis-9,trans-12-dien-1-ol (42521-46-0,51937-00-9)

Guidance literature:

With sodium hydroxide; In methanol;

upstream raw materials:

Tetradec-9Z,12E-dien-1-yl Acetate

1-<(tetrahydro-2H-pyran-2-yl)oxy> 9Z, 12E-tetradecadiene

(E)-Tetradec-12-en-9-yn-1-ol

2-dec-9-ynyloxy-tetrahydro-pyran

Downstream raw materials:

Tetradec-9Z,12E-dien-1-yl Acetate

(Z)-undec-9-en-1-ol

(Z,E)-9,12-tetradecadienal

(Z,Z)-9,12-tetradecadienyl acetate

Refernces

• 1、 Herbert, Myles B.,Marx, Vanessa M.,Pederson, Richard L.,Grubbs, Robert H.. "Concise syntheses of insect pheromones using Z-Selective cross metathesis". supporting information. p. 310 - 314. Retrieved 2013/02/23.
• 2、 Hornyanszky, Gabor,Rohaly, Janos,Novak, Lajos. "Facile synthesis of mill moth's sex pheromone components". . p. 1533 - 1540. Retrieved 2008/09/20.