Carbamodithioic acid, (phenylmethyl)-, compd. with N,N-diethylethanamine (1:1)

Base Information

• Chemical Name: Carbamodithioic acid, (phenylmethyl)-, compd. with N,N-diethylethanamine (1:1)
• CAS No.: 43009-20-7
• Molecular Formula: C8H9NS2.C6H15N
• Molecular Weight: 284.49
• Mol file: 43009-20-7.mol

Synonyms:

Chemical Property of Carbamodithioic acid, (phenylmethyl)-, compd. with N,N-diethylethanamine (1:1)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamodithioic acid, (phenylmethyl)-, compd. with N,N-diethylethanamine (1:1)

There total 1 articles about Carbamodithioic acid, (phenylmethyl)-, compd. with N,N-diethylethanamine (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

carbon disulfide (75-15-0,12122-00-8) + triethylamine (121-44-8) + benzylamine (100-46-9) → triethylammonium N-benzyldithiocarbamate (43009-20-7)

Guidance literature:

In diethyl ether; at 0 ℃; for 72h;

DOI:10.3184/030823409X12561978806846

Reference yield: 97.0%

triethylammonium N-benzyldithiocarbamate (43009-20-7) → Benzyl isothiocyanate (622-78-6)

Guidance literature:

With iodine; triethylamine; In acetonitrile; at 5 ℃; Cooling with ice;

DOI:10.1002/ejoc.200801270

Reference yield: 90.0%

triethylammonium N-benzyldithiocarbamate (43009-20-7) + cyclohexylamine (108-91-8,157973-60-9) → 1-benzyl-3-cyclohexylthiourea (78080-33-8)

Guidance literature:

With ammonium cerium (IV) nitrate; oxygen; In acetonitrile; at 20 ℃; for 12h;

DOI:10.1039/c4ra04628e

upstream raw materials:

carbon disulfide

triethylamine

benzylamine

Downstream raw materials:

2'-amino-3-benzyl-2-thioxo-2,3-dihydro-[5,5']bithiazolylidene-4,4'-dione

5-benzoylmethyl-3-benzyl-2-thioxo-4-thiazolidinone

3-benzyl-5-[2-(4-chlorophenyl)-2-oxoethyl]-4-oxo-2-thioxo-1,3-thiazolidine

N-Benzyl-dithiocarbaminsaeure-(kohlensaeuremono-aethylester)-anhydrid

Refernces

• 1、 Zhu, Daqian,Wu, Zhouming,Liang, Liyun,Sun, Yameng,Luo, Bingling,Huang, Peng,Wen, Shijun. "Heterocyclic iodoniums as versatile synthons to approach diversified polycyclic heteroarenes". . p. 33170 - 33179. Retrieved 2019.
• 2、 Janczewski, ?ukasz,Gajda, Anna,Frankowski, Sebastian,Goszczyński, Tomasz M.,Gajda, Tadeusz. "T3P - A Benign Desulfurating Reagent in the Synthesis of Isothiocyanates". . p. 1141 - 1151. Retrieved 2017/12/06.