sodium phenylglyoxylate

Base Information

• Chemical Name: sodium phenylglyoxylate
• CAS No.: 43165-51-1
• Molecular Formula: C8H6O3.Na
• Molecular Weight: 172.116
• Hs Code.: 2918300090
• Mol file: 43165-51-1.mol

Synonyms:sodium salt of benzoylformic acid;phenylglyoxylic acid sodium salt;Sodium phenylglyoxylate;sodium benzoyl formate;EINECS 256-125-8;phenyl-glyoxylic acid,sodium-compound;sodium benzoylformiate;Benzeneacetic acid,a-oxo-,sodium salt;

Chemical Property of sodium phenylglyoxylate

Chemical Property:

• Vapor Pressure: 0.00697mmHg at 25°C
• Boiling Point: 258.6oC at 760 mmHg
• Flash Point: 124.4oC
• PSA: 57.20000
• LogP: -0.38080

Purity/Quality:

98%Min ^*data from raw suppliers

SodiumPhenyl-d5-glyoxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium phenylglyoxylate

There total 2 articles about sodium phenylglyoxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Benzoylformic acid (611-73-4) → sodium benzoylformate (43165-51-1)

Guidance literature:

With sodium hydroxide; In methanol; at 20 ℃; for 2h;

DOI:10.1039/d0cc05942k

Reference yield:

(R)-Mandelsaeure, Natrium-Salz (54385-47-6) → sodium benzoylformate (43165-51-1)

Guidance literature:

With tris hydrochloride; nicotinamide adenine dinucleotide; In water; at 30 ℃; pH=7.5; Enzyme kinetics;

DOI:10.1271/bbb.70827

Reference yield: 98.0%

sodium benzoylformate (43165-51-1) + Azobenzene (1227476-15-4) → N,N'-diphenylbenzohydrazide (970-26-3)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 24h; Solvent; Irradiation;

DOI:10.1021/acs.orglett.0c03039

upstream raw materials:

(R)-Mandelsaeure, Natrium-Salz

Benzoylformic acid

Downstream raw materials:

Oxo-phenyl-acetic acid (S)-1-tert-butyl-pentyl ester

phenylglyoxylyl chloride

(R)-Mandelic Acid

4-chlorobenzyl 2-oxo-2-phenylacetate

Refernces

• 1、 Wada, Yusuke,Iwai, Saho,Tamura, Yusuke,Ando, Tomonori,Shinoda, Takeshi,Arai, Kazuhito,Taguchi, Hayao. "A new family of D-2-hydroxyacid dehydrogenases that comprises D-mandelate dehydrogenases and 2-ketopantoate reductases". . p. 1087 - 1094. Retrieved 2008/09/21.